دانلود کتاب The Conservation of Orbital Symmetry

فهرست مطالب :

1. Introduction ... 1 2. Orbitals and Bonding ... 2 3. Correlation Diagrams ... 10 3.1 General Comments on the Construction of Correlation Diagrams .. 27 3.2 Precautions in the Construction of Correlation Diagrams .. 31 4. The Conservation of Orbital Symmetry ... 37 5. Theory of Electrocyclic Reactions ... 38 5.1 Electrocyclic Reactions Exemplified .. 48 6. Theory of Cycloadditions and Cycloreversions ... 65 6.1 Cycloadditions and Cycloreversions Exemplified .. 73 6.2 [2+2] Cycloadditions in the Photochemistry of the Cyclohexadienones and Cyclohexenones .. 89 6.3 The [2+2+2] Cycloaddition Reaction .. 101 6.4 Prismane .. 107 6.5 [2+2+2+2] Cycloadditions .. 112 7. Theory of Sigmatropic Reactions ... 114 7.1 Sigmatropic Reactions Exemplified .. 120 7.2 Sequential Sigmatropic Shifts .. 132 8. Group Transfers and Eliminations ... 142 9. Secondary Effects ... 145 10. Divertissements! ... 152 10.1 Cheletropic Reactions .. 152 10.2 Cycloaddition Reactions of Ketenes .. 163 11. Generalized Selection Rules for Pericyclic Reactions ... 170 12. Violations ... 173 13. Other Theoretical Work ... 176 14. Conclusion ... 178 {ymw}