دانلود کتاب Electrochemical Carbon Dioxide Reduction

فهرست مطالب :

Cover
Half Title
Also of Interest
Electrochemical Carbon Dioxide Reduction
Copyright
Contents
1. Introduction to electrochemical carbon dioxide reduction
1.1 The role of electrochemical CO2 reduction in global decarbonisation
1.2 CO2 reduction to value-added materials
1.2.1 Carbon monoxide and syngas
1.2.2 Formic acid
1.2.3 Methane and methanol
1.2.4 Ethylene and ethanol
1.2.5 Additional products
1.3 Primary challenges
1.3.1 Single product selectivity
1.3.2 Changes to the solution environment
1.3.3 Carbon costs
1.3.4 Financial costs
1.3.5 Stability to continued operations
1.3.6 Key targets
2. Reaction mechanisms
2.1 C1 product route
2.1.1 Formate and formic acid
2.1.2 Carbon monoxide
2.1.3 Methane and methanol
2.2 C2 product route
2.2.1 Ethylene and ethanol
2.2.2 C3+ and beyond
2.3 Computational activity predictors and scaling relationships
2.4 Hydrogen evolution reaction
3. Catalyst design
3.1 Carbon monoxide and syngas
3.2 Formate and formic acid
3.3 Copper catalysts
3.3.1 Methane and methanol
3.3.2 Ethylene and ethanol
3.3.3 Acetate and acetic acid
3.3.4 Propanol
3.4 Tandem catalysts
3.5 Non-copper catalysts for higher order products
4. Electrolytes
4.1 Aqueous electrolytes
4.1.1 pH
4.1.2 Anions
4.1.3 Cations
4.2 Organic solvents
4.2.1 Aprotic solvents
4.2.2 Hydrated organic solvents
4.2.3 Protic organic solvents
4.3 Ionic liquids
4.3.1 Cation effects
4.3.2 Protonation steps in ionic liquids
4.3.3 Cheaper catalyst materials
5. Reactor engineering
5.1 Electrode architectures
5.1.1 Foil and mesh electrodes
5.1.2 Nanostructured materials
5.1.3 Gas diffusion electrodes
5.1.4 Polymer coatings and additives
5.2 Reactor designs
5.2.1 Divided and undivided reactors
5.2.2 Flow cells
5.2.3 Zero-gap cells
5.2.4 Microfluidic devices
5.2.5 Reactor pressure, CO2 partial pressure and temperature
6. Future perspectives
6.1 High-priority research focus
6.1.1 Extended operations
6.1.2 Enhanced selectivity
6.1.3 Considering the anode
6.2 Complimentary technologies
6.2.1 Green energy security
6.2.2 Multi-synthesis reactors
6.2.3 Broader considerations
References
Index