دانلود کتاب Fluorine: A Paradoxical Element: Volume 5 (Progress in Fluorine Science)

فهرست مطالب :

0
Quotation_2019_Fluorine
Quotation
Front-Matter_2019_Fluorine
Front Matter
Copyright_2019_Fluorine
Copyright
Foreword_2019_Fluorine
Foreword
Introduction_2019_Fluorine
Introduction
1
History and milestones of fluorine and fluorinated products through the centuries
History and uses of fluorinated minerals
Fluoride crystals as gemstones substitutes
Fluorinated powders as “therapeutics´´
Uses of fluorspar minerals as pigments
Uses of fluorspar as ornaments and in decoration items
Middle ages forgeries: Fossilized mastodon tusks sold as synthetic ``turquoise´´
Fluorine dating in archeology
Relative dating of bones and skeletal remains
The Piltdown hoax and the Tepexpan man
Early hominid remains
Earliest modern human skeletons in Japan and East Asia
Limits of the method
Dating archeological lithic artifacts by fluorine diffusion
Dating bronze-age arrowhead flintstones of Fort-Harrouard, France
Following trading routes in South Pacific islands using obsidian artifacts
The true nature of the Roman murrhine through a critical lecture of Pliny the Elder\'s ``Naturalis Historia´´
Georgius Agricola, the father of mineralogy and creator of the word ``fluoride´´
In search of the missing halogen, from the Renaissance to 1886
The isolation of fluorine on June 1886 by a pharmacist and chemist: Henri Moissan
Physical chemical characteristics of fluorine
Some breakthroughs in the development of fluorine and fluorinated products throughout the 20th century
The rapid growth of the aluminum industry
1886, a great year for both fluorine and aluminum: The Hall-Héroult process
Improvement of the production process of aluminum by addition of fluorinated fluxes
Production processes
The anode effect and PFC formation
Application fields for aluminum
The rise and fall of CFC
A new type of ``too perfect´´ refrigerants
Phasing out CFCs and HCFCs
Ozone depletion, the Montreal and Kyoto Protocols
The story of Teflon and fluoropolymers
The discovery of Teflon
Fluoropolymers: From military applications to hospital and kitchen uses
Fluorine, a decisive element in the nuclear cycle
The Manhattan project
Importance of fluoride materials in the nuclear cycle
2
Fluorine, a key element for the 21st century
Advances in organic fluorine chemistry
Toward new functional molecules
The carbon-fluorine bond
Some examples of fluoro-organic chemistry
Electrophilic fluorination
Electrofluorination
Nucleophilic fluorination
Deoxofluorination
Fluorinated building blocks
Fluorous chemistry
Click Chemistry of Sulfur Fluoride Exchange (SuFEx)
Superacid Media
Advances in new fluorination routes, surface functionalization, and nanosized fluorocompounds
Frontiers in inorganic fluorine chemistry
Some routes to high oxidation states of transition elements
On new polynitrogen [N5]+ species
Looking for the ``naked´´ fluoride ion
Fluorolytic sol-gel method to produce high surface area nanofluorides154154St. Rüdiger, G. Eltanany, U. Gross, E. Ke ...
Aluminium chlorofluoride as catalyst in CFC and HCFC test-reactions
Use of nanofluorides for various types of coatings
Nanoporous solids and organo-inorganic hybrid compounds
Functionalization of materials via surface fluorination
Surface modification of carbon-based materials for Li-battery electrodes
Functionalized silica and silicate minerals
Switchable hydrophobic-hydrophilic layer for lithographic printing
Improvements of polymer properties through fluorination
Fluoropolymers for the protection of our cultural heritage
Protection of the surface of the stones
Anti-graffiti systems
Industrial applications of fluoride minerals, gases, and inorganic fluorinated products
Applications of inorganic fluorinated products
Contributions of fluorinated products to energy problems
Diversity of fluorinated components in lithium-ion batteries
Primary Li-ion batteries
Secondary/reversible Li-ion batteries
Electrodes based on transition element fluorides
All-solid fluoride ion batteries
Polymer fuel cells
Uses of fluorides in photonics
Luminescence; up- and down-conversion
Optically active single-crystals of fluorides: the example of LiCaAlF6
Fluoro-glasses, (oxy)fluorinated glass-ceramics
Other uses in photonics: Non-linear optical fluorides, photochromic and holographic fluorocompounds, excimer KrF lasers
Bistable centers in semi-conducting fluorite crystals: media for real-time holography
Krypton fluoride lasers
Fluorinated components in photovoltaic systems
Transparent conducting films based on fluorine-doped tin oxide (FTO)
Fluorinated components in dye-sensitized solar cells (DSSC)
Fluorinated photoelectrode in QDSSC (quantum dot-sensitized solar cell)
Fluoro co-polymers for membranes in DSSC systems
Fluorinated components in perovskite solar cells
Uses of fluorides in electronics and other modern technologies
New fluorinated carbon materials for electronics
Fluorinated organic compounds for molecular electronics
Recent uses of fluoro-copolymers
Fluorinated colored pigments and UV absorbers for solar protection
High TC superconductors obtained by insertion of fluorine into oxides and oxypnictides (La2CuO4, LaFeAsO, BiS2 layer ...
Magnetism and multiferroism in fluorides
Ferro- and ferrimagnetic fluorides
Other types of magnetic behaviors
Pd2F6 and MIIMIVF6 compounds as piezo-conductive species
Multiferroic fluoride materials
The BaMF4 series
The TTB fluorides series KxMxIIM5-xIIIF15
Other multiferroic ABF3 fluoroperovskites
Contributions of fluorinated products in medicine, pharmacy, and biotechnologies
Fluorinated products in biochemistry and medicinal chemistry
New drugs
New 18F fluoride-based radiotracers for positron emission tomography (PET imaging)
Fluorinated products for magnetic resonance imaging (MRI)
Photodynamic therapy (PDT)
Perfluorocarbons in medicinal technologies: Contrast agents, artificial blood, retinal surgery
Contrast agents in ultrasound or magnetic resonance technologies
PFCs as blood substitutes
PFCs as respiratory gas transport agent
PFCs in retinal surgery
PFCs in cosmetics
Fluorinated compounds as bio-materials
Prophylactic effect of fluorine and fluorinated dental biomaterials
Bioceramics and fluorinated biomaterials
Fluorinated silicates in cosmetics
Fluorinated polymers in cardiovascular surgery
Plant protection products and insecticides
3
Fluorinated compounds in our environment: Fluorine, friend or foe for humanity?
Genesis and cosmo-chemistry of fluorine
The discovery of fluorinated molecules in interstellar space
The enigma of the genesis of fluorine
First discovery of fluorine on Mars with ChemCam on-board MSL-curiosity
Presence of fluorine in Martian and lunar meteorites found on Earth
Determination of the residence time of meteorites on Antarctica surface through ion beam analyses
Fluorine and our atmosphere
The fragile balance of our planet
Stratospheric phenomena
Tropospheric phenomena
The total fluoride cycle: Evaluation of average fluorine levels in our environment
The global cycle of fluorine
Assessing the rates of fluorine present in our environment
Evaluation of the fluorine content in air
Evaluation of the fluorine content in seawater
Fluorine content in freshwaters
Fluorine in rocks and various types of soils
The various fluorinated gases: Halocarbons, perfluorocarbons, SF6
Environmental impact
HFCs and fluorinated ethers as substitutes for CFCs and HCFCs
Perfluorocarbons
Sulfur hexafluoride
Control and limitation of emissions of fluorinated gases in relation to the risks of climate change
Control of emissions of fluorinated gases
Control and limitation of fluorinated greenhouse gases (GHG)
Contribution of fluorinated greenhouse gases to radiative forcing
What substitutes for CFCs, HCFCs, and HFCs?
Fluorine and the lithosphere
Natural fluorinated compounds present in our environment and the various sources of fluorine
Discovery of fluorine gas (F2) on earth
The fluorinated minerals
Main families of fluorinated minerals
Recovery of byproducts of mineral fluoride industries
Recovery of byproducts of mineral fluoride industries
The case of perfluorinated compounds of geological origin
Fluorinated organic molecules present in plants
Emissions of fluorinated gases of volcanic origin
Risks associated with volcanic eruptions with halide/fluoride emissions
Two examples of volcanoes emitting gas and fluorinated solids
Recent eruptions of Hekla (Iceland)
Emission of fluorine at Erebus volcano (Antarctica)
Emissions of anthropogenic origin
Example of the ceramic industries
Manufacturing processes
Monitoring and purification system
Processes involving coal
Domestic coal heating
Coal-based thermal power plants
Technologies allowing a reduction of fluorine emissions in coal-fired power plants
Aluminum industry and overall assessment of the greenhouse effect
Life cycle assessment of aluminum
Impact of the aluminum industry on PFC emissions
Fluorine in the water cycle
Hydrochemistry of fluorine in groundwater
Fluorine content of groundwater
Influence of hydro-climatic conditions in countries with high risk of fluorosis
Fluorine, friend or foe for human health?
Levels of fluorine in food
International standards for drinking water and water fluoridation
Importance of fluoride in oral health
Possible use of fluorinated salts in the treatment of osteoporosis
Bioassimilation of fluoride in humans and animals
Contamination and physiological effects of fluoride on living organisms
Water contamination and fluorosis
Food contamination by tea bricks
Environmental contamination
Industrial and domestic contamination: Example of the use of coal
The ban of persistent organic pollutants (POP): The case of PFOS and PFOA
Improving the quality of drinking water by defluoridation
Precipitation processes
Adsorption and ion exchange processes
Nanofiltration (NF)
Reverse osmosis
4
Conclusions: What future for fluorine and fluorine products?
5
Books on fluorine chemistry and fluoride products (2000-2018)
6
Index
A
B
C
D
E
F
G
H
I
J
K
L
M
N
O
P
Q
R
S
T
U
V
W
X
Z
7
Acronyms and definitions quoted in the text
Acronyms
Definitions
8
Acknowledgments