دانلود کتاب Gambur Y.D.

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Cover
Half Title
The Fundamentals of Electrochemistry
Copyright
Table of Contents
Preface
List of Symbols
1. Introduction: General Issues
1.1. Subject, features, structure, and areas of interest of electrochemistry
1.2. The main historical stages of the development of electrochemistry. The place of electrochemistry among other sciences and its prospects
1.3. Faraday\'s laws and current efficiency
2. Equilibrium Properties of Electrolytes
2.1. Ions in electrolyte solutions: Electrolytic dissociation
2.2. Ion-dipole and ion-ion interactions in solutions: Interaction potentials
2.3. Ion solvation
2.4. Solvents in electrochemistry
2.5. Nonideality of solutions: Activity and chemical potential
2.6. Ionic equilibria in solutions
2.7. Theory of strong electrolytes
2.8. Correlation methods for calculating interactions between particles in electrolyte solutions
3. Nonequilibrium Phenomena in Electrolyte Solutions
3.1. Ionic transport in solutions; conductivity
3.2. Molar electrical conductivity
3.3. Transport (transfer) numbers
3.4. Electrical conductivity of highly diluted solutions of strong electrolytes
3.5. Diffusion in electrolyte solutions
3.6. Nernst–Einstein equation
3.7. General equation for the ion flux
3.8. The average diffusion coefficient of the electrolyte
3.9. Electrical conductivity of melts
3.10. Electrical conductivity of solid electrolytes
3.11. Polymer electrolytes
4. Electrochemical Systems and Electrode Potentials
4.1. Electrodes
4.2. Electrode potentials
4.3. External, inner, and surface potentials; Volta potential and Galvani potential
4.4. The Nernst equation
4.5. The standard potential
4.6. Classification of the electrodes
4.7. Gas electrodes. Standard Hydrogen Electrode (SHE)
4.8. Reference electrodes and indicator electrodes. Sensors
4.9. Membrane electrodes
4.10. Glass electrode
4.11. Other types of electrochemical sensors
4.12. Electrochemical cells: rules for notations
4.13. Influence of various conditions on the voltage of the electrochemical cell
4.14. Potentiometry and electrochemical cells
4.15. Experimental determination of the standard potential
5. Double Electric Layer and Adsorption of Substances on Electrodes
5.1. Processes at the phase boundaries
5.2. Adsorption isotherms
5.3. Dependence of adsorption on the electrode potential: Electrocapillarity
5.4. Double layer capacitance measurements
5.5. Structure of the double electric layer.
5.6. Graham’s Model
5. 7. Structure of the double electric layer and the rate of electrode processes
6. Electrochemical kinetics
6.1. Polarization of the electrodes: Practical measurement of the electrode potential during polarization
6.2. The concept of overpotential
6.3. Limiting stages of processes
6.4. Potential diagrams
6.5. Energy variation in electrode processes
6.6. Theoretical concepts of the elementary act of electron transfer
6.7. Quantum chemistry considerations
6.8. Exchange current: The shape of the polarization curves
6.9. Charge transfer on semiconductors
6.10. Mass transport in the kinetics of electrode processes: Diffusion layer
6.11. The role of convection and the thickness of the diffusion layer: The limiting current density
6.12. Concentration (diffusion) overpotential
6.13. The role of convection and migration: Mixed kinetics
6.14. Quantitative accounting of migration
6.15. Voltage drop in the diffusion layer
6.16. The mechanism of processes: Multistage processes
7. Electrochemical Methods
7.1. Steady-state polarization curves
7.2. Cyclic voltammetry
7.3. Study of parallel electrode reactions
7.4. Decomposition of the full polarization curve into partial ones
7.5. Rotating disk electrode (RDE) method
7.6. The method of a rotating ring-disk electrode (RRDE)
7.7. Comparing the rates of the stages and determining the mechanism of the process
7.8. Some problems of non-steady state diffusion and relaxation methods for studying electrode processes
7.9. Changes in concentrations, currents, and potentials during the passage of alternating current
7.10. The electrochemical impedance spectroscopy (EIS)
7.11. Thin-layer cells and microelectrodes
7.12. Polarography on a mercury dropping electrode
7.13. Theory of the method. Diffusion to a spherical surface
7.14. Non-electrochemical research methods in electrochemistry
7.15. Studies of surfaces and surface phenomena: Research of solid materials
8. Electrochemical Processes at Metal Deposition
8.1. General remarks
8.2. Overpotential of metal electrodeposition
8.3. Processes during the growth of a new phase
8.4. Electrochemical phase formation via nucleation
8.5. Surfactants in the electrodeposition of metals.
8.6. Electrodeposition from complex electrolytes.
8.7. Electrodeposition from melts
8.8. Electrodeposition of alloys
8.9. Adatoms and underpotential deposition
8.10. Metal distribution over the electrode surface
8.11. Microdistribution of current over a rough surface
8.12. Leveling and brightening
9. Anodic Dissolution and Corrosion of Metals
9.1. Thermodynamics, kinetics, and mechanism of anodic dissolution
9.2. Passivation of metals
9.3. Practical application of passivation and activation
9.4. Pitting corrosion: The mechanism of pitting formation
9.5. Transpassive dissolution of metals in electrochemical technology
9.6. Electrochemical corrosion of metals
9.7. Processes in autonomous and short-circuited electrochemical systems
9.8. Pourbaix Diagrams
10. Some Modern Aspects of Applied Electrochemistry
10.1. Electrocatalysis: Electrode materials in technology
10.2. Catalytic activity and its relation to the work function of the electron work function and other properties of materials
10.3. Non-metallic coating layers and their use in anodic processes
10.4. Porous electrodes
10.5. Electrochemical hydrogen evolution reaction (HER)
10.6. Hydrogenation of metals
10.7. Isotopic effect
10.8. Reactions of electrochemical reduction and cathodic evolution of oxygen
10.9. Production of chlorine
10.10. Electrochemical reactions involving organic substances
10.11. Applications of cathodic deposition of metals and alloys
10.12. Galvanic cells
10.13. Requirements for galvanic cells (batteries)
10.14. Types of electrochemical power sources: Primary batteries
10.15. Rechargeable batteries
10.16. Novel chemical power sources
10.17. Fuel cells
1. The process on the cathode.
2. The process on the anode.
10.18. Environmental aspects of electrochemical technologies; electrochemical methods of water purification
10.19. Electric field in the cells and current distribution over the electrode surface
10.20. Primary and secondary current distribution
10.21. The throwing power of the electrolyte
Subject Index