دانلود کتاب Grafted Biopolymers as Corrosion Inhibitors: Safety, Sustainability, and Efficiency

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Cover
Half Title
Wiley Series in Corrosion
Grafted Biopolymers as Corrosion Inhibitors: Safety, Sustainability, and Efficiency
Copyright
Contents
About the Editors
List of Contributors
Preface
Part 1. Economic and Legal Issue of Corrosion
1. Corrosion: Basics, Economic Adverse Effects, and its Mitigation
1.1 The Basics of Corrosion
1.2 Corrosion Mitigations
1.3 Corrosion and its Economic Adverse Effects
1.4 Conclusion
References
2. Corrosion Inhibition: Past and Present Developments and Future Directions
2.1 Introduction
2.2 Grafting of Biopolymer
2.3 Grafted Biopolymers for the Corrosion Protection
2.4 Conclusion and Future Prospective
References
3. Biopolymers as Corrosion Inhibitors: Relative Inhibition Potential of Biopolymers and Grafted Biopolymers
3.1 Introduction
3.2 Biopolymers as Corrosion Inhibitors
3.3 Structural and Chemical Characteristics of Biopolymers
3.4 Grafted Biopolymers
3.5 Factors that Influence Grafting Efficiency/Percentage
3.6 Chemical Characteristics of Polysaccharides as Corrosion Inhibitors
3.7 Structural Modifications in Biopolymers and Effect of Intensifiers
3.8 Grafted biopolymers Versus Biopolymers
3.9 Corrosion Tests
3.9.1 Effect of Concentration
3.9.2 Effect of Immersion Time
3.9.3 Effect of Temperature and Inhibition Mechanism
3.10 Metallic Alloys and Surface Characterization
3.11 Computational Studies, in Silico Methods
3.12 Gaps and Future Trends
Acknowledgments
References
4. Biopolymers vs. Grafted Biopolymers: Challenges and Opportunities
Challenges and Opportunities
4.1 Introduction
4.1.1 Biopolymers
4.2 Classification
4.3 Opportunities
4.4 Ecological Applications of Biopolymers
4.5 Cellulose
4.6 Cotton
4.7 Regenerated Cellulose
4.8 Rayon
4.9 Cellophane
4.10 Cellulose Derivatives
4.10.1 Cellulose Acetate
4.10.2 Cellulose Nitrate
4.11 Starch
4.12 Silk Fibroin
4.13 Wool
4.14 Proteins
4.15 Collagen
4.16 Chitosan
4.17 Challenges of Biopolymers
4.18 Grafted Biopolymers
4.18.1 Opportunities
4.19 Challenges
4.20 Conclusion
References
Part 2. Overview of Sustainable Grafted Biopolymers
5. Sustainable Grafted Biopolymers: Synthesis and Characterizations
5.1 Introduction
5.2 Grafted Biopolymers: Synthesis and Characterizations
5.2.1 Grafted Polysaccharides
5.2.2 Modification of Polysaccharides by Microwaves
5.2.3 Grafted Chitosan Derivatives
5.2.4 Crosslinked Chitosan Derivatives
5.2.5 Chitosan Methacrylate Derivatives
5.2.6 Targeted Chitosan Modification
5.3 Conclusions
References
6. Sustainable Grafted Biopolymers: Properties and Applications
6.1 Introduction
6.2 Properties
6.3 Applications
6.3.1 In Food Industry
6.3.2 In Pharmaceutical Industry
6.3.3 For Sustainable Development
6.4 Application of Grafted Biopolymers in Corrosion Inhibition
6.4.1 Copper
6.4.2 Steel
6.4.3 Pectin
6.4.4 Chitosan
6.4.5 Mucilage
6.4.6 Chitin
6.4.7 k-Carrageenan
6.4.8 Starch
6.4.9 Cellulose
6.4.10 Alginate
6.4.11 Dextrin
6.4.12 Polyacrylamide
6.4.13 Glucomannan
6.4.14 Gum
6.5 Future Scope
6.6 Conclusion
References
7. Factors Affecting Biopolymers Grafting
7.1 Introduction
7.2 Nature of the Backbone
7.3 Effect of Monomer
7.4 Effects of Solvent
7.5 Effect of Initiator
7.6 Role of Additives on Grafting
7.7 Effects of Temperature
7.8 Conclusion
References
Part 3. Sustainable Grafted Biopolymers as Corrosion Inhibitors
8. Corrosion Inhibitors: Introduction, Classification and Selection Criteria
Abbreviations
8.1 Introduction
8.2 Chemistry and Adverse Impact of Corrosion
8.3 Corrosion Inhibitors
8.4 Corrosion Inhibitor Classification
8.4.1 Electrode Process-Based
8.4.2 Based on Environment
8.4.3 Based on Mode of Protection
8.5 Selection Criteria for Inhibitors
8.6 Mechanism of Corrosion Inhibition
8.7 Industrial Application of Corrosion Inhibition
8.7.1 In Concrete
8.7.2 In Cooling Water Systems
8.7.3 Acid Pickling
8.8 Summary
References
9. Methods of Corrosion Measurement: Chemical, Electrochemical, Surface, and Computational
9.1 Introductions
9.2 Corrosion Measurements
9.2.1 Non-electrochemical Method for Corrosion Monitoring
9.2.2 Electrochemical Methods for Corrosion Monitoring
9.3 Surface Characterization Methods
9.3.1 X-ray Photoelectron Spectroscopy (XPS)
9.3.2 X-ray Diffraction (XRD)
9.3.3 Scanning Electron Microscopy (SEM)
9.3.4 Atomic Force Microscopy (AFM)
9.4 Computational Methods
9.4.1 Density Functional Based Theoretical Methods
9.4.2 Molecular Dynamics (MD) Simulation
9.5 Conclusions
Acknowledgment
References
10. Experimental and Computational Methods of Corrosion Assessment: Recent Updates on Concluding Remarks
10.1 Introduction
10.2 Chemical Methodologies
10.2.1 Gravimetric Methods
10.2.2 Effect of Inhibitor Dosage and Temperature
10.2.3 Effect of Exposure Periods
10.2.4 The Thermodynamic & Activation Parameters
10.2.5 Adsorption Isotherms
10.3 Electrochemical Methodologies
10.3.1 Open Circuit Potential
10.3.2 Electrochemical Impedance Spectroscopy
10.3.3 Potentiodynamic Polarization
10.4 Surface Characterizations
10.4.1 Scanning Electron Microscopy
10.4.2 Atomic Force Microscopy
10.4.3 Chemical Composition Analysis of Substrate Surface
10.5 Computational Methodologies
10.5.1 Density Functional Theory (DFT)
10.5.2 Molecular Dynamics Simulation Studies
References
11. Grafted Natural Gums Used as Sustainable Corrosion Inhibitors
11.1 Introduction
11.2 Gum-based Corrosion Inhibitors
11.3 Application of Grafted Gums as Corrosion Inhibitors
11.4 Conclusion and Perspectives
Useful Links
References
12. Grafted Pectin as Sustainable Corrosion Inhibitors
12.1 Introduction
12.2 Pectins as Corrosion Inhibitors
12.3 Pectins Grafted Derivatives as Corrosion Inhibitors
12.4 Prospects and Challenges
Acknowledgments
Declaration of Competing Interest
References
13. Grafted Chitosan as Sustainable Corrosion Inhibitors
13.1 Introduction
13.1.1 Importance of Grafted Chitosan as Sustainable Corrosion Inhibitors
13.2 Main Part
13.2.1 Grafted Chitosan-Based Compounds as Sustainable Anti-corrosion Agents for Steel-based Materials: Theoretical and Investigational Insights
13.2.2 Grafted Chitosan Based-Compounds as Sustainable Anti-corrosion Agents for Copper-Based Materials: Investigational and Theoretical Insights
13.2.3 Grafted Chitosan Derivatives as Sustainable Corrosion Inhibitors for Aluminium-Based Materials: Experimental and Theoretical Insights
13.3 Conclusion and Future Perspective
References
14. Grafted Starch Used as Sustainable Corrosion Inhibitors
14.1 Introduction
14.1.1 Inhibition of Metallic Corrosion via Chemical Compounds
14.2 Starch Structure, Composition and Modification
14.3 Application of Starch and Modified Starch as Corrosion Inhibitors
14.4 Utilization of Grafted Starch as Effective and Sustainable Corrosion Inhibitors
14.4.1 Grafted Cassava Starch as Eco-Friendly Corrosion Inhibitors
14.4.2 Miscellaneous Grafted Starch as Eco-Friendly Corrosion Inhibitors
14.5 Conclusions
References
15. Grafted Cellulose as Sustainable Corrosion Inhibitors
15.1 Introduction
15.1.1 Cellulose
15.1.2 Carboxymethyl cellulose and its derivatives
15.1.3 Cellulose Acetate and its Derivatives
15.1.4 Methylcellulose, ethyl cellulose, propyl cellulose and their derivatives
15.1.5 Other cellulose derivatives
15.1.6 Synergistic effect in cellulose-based inhibition systems
15.2 Conclusion
References
16. Sodium Alginate: Grafted Alginates as Sustainable Corrosion Inhibitors
16.1 Introduction
16.2 Types of Biopolymers
16.2.1 Microbial Biopolymers
16.2.1.1 Bacterial Biopolymers
16.2.1.1.1 Polysaccharides
16.2.1.1.2 Polyamides
16.2.1.1.3 Polyesters
16.2.1.1.4 Polyphosphates
16.2.1.2 Fungal Biopolymers
16.2.1.3 Algal Biopolymers
16.2.2 Plant Biopolymers
16.3 Biopolymers as Antifouling Agents
16.4 Sodium Alginate
16.4.1 Producers of Sodium Alginate
16.4.2 Extraction and Characterization of Sodium Alginate
16.4.2.1 Moisture Content
16.4.2.2 Viscosity
16.4.2.3 Whiteness Degree
16.4.2.4 UV Spectroscopy
16.4.2.5 FTIR Spectroscopy
16.4.2.6 X-Ray Diffraction
16.4.2.7 Differential Scanning Calorimetry
16.4.2.8 Thermogravimetric Analysis
16.4.3 Material Formulations of Sodium Alginate
16.4.3.1 Hydrogels
16.4.3.2 Microspheres
16.4.3.3 Fibres
16.4.3.4 Composites
16.4.3.5 Films
16.4.3.6 Other Formulations
16.4.4 Sodium Alginate Grafting
16.4.5 Sodium Alginate in Anti-Fouling
16.4.6 Biomedical Applications of Sodium Alginate
16.4.7 Sodium Alginate in Cell Culture
16.5 Conclusion
Acknowledgement
References
17. Grafted Dextrin as a Corrosion Inhibitor
17.1 Corrosion and Its Adverse Impact
17.2 Corrosion Inhibitors and Factors Affecting Their Efficiency
17.3 Biopolymers as Corrosion Inhibitors: Advantages and Disadvantages
17.4 Methods of Grafting the Biopolymers
17.5 Grafted Dextrin as Corrosion Inhibitor: A Literature Survey
17.6 Conclusion and Future Scope
Acknowledgments
Conflict of Interest Statement
Competing Interest Statement
Author’s Contributions
References
18. Grafted Biopolymer Composites and Nanocomposites as Sustainable Corrosion Inhibitors
18.1 Introduction
18.2 Corrosion – Headache to Industrial Pipelines
18.3 Biopolymers – Production and Applications
18.3.1 Applications of Biopolymers
18.3.2 Production of Biopolymers
18.4 Nanocomposites – Production and Applications
18.4.1 Applications of Nanocomposites in Biotechnology
18.5 Role of Composites and Nanocomposites in Corrosion Inhibition
18.6 Green Chemistry in Corrosion Inhibition
18.6.1 Mechanism of Action of Green Inhibitors
18.7 Environmental Safety Aspects on Industrial Outlooks
18.8 Conclusion and Future Directions
Acknowledgment
Conflict of Interest
References
19. Industrially Useful Corrosion Inhibitors: Grafted Biopolymers as Ideal Substitutes
19.1 Introduction
19.2 Corrosion Inhibitors
19.2.1 Sustainable or Green Corrosion Inhibitors
19.2.2 Guidelines and Assessment of the Sustainability of Corrosion Inhibitors
19.2.3 Industrial Uses of Corrosion Inhibitors
19.3 Biopolymers
19.3.1 Classification of Biopolymers
19.3.2 Applications of Biopolymers
19.4 Biopolymers as Corrosion Inhibitors
19.4.1 Sugar-Based Biopolymers
19.4.2 Dextrin and Cyclodextrin
19.4.3 Cellulose as Corrosion Inhibitors
19.4.4 Starch as Corrosion Inhibitors
19.5 Conclusion
References
Index