دانلود کتاب Heterogeneous Catalysis in Sustainable Synthesis (Advances in Green and Sustainable Chemistry)

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Front-Matter_2022_Heterogeneous-Catalysis-in-Sustainable-Synthesis
Front Matter
Copyright_2022_Heterogeneous-Catalysis-in-Sustainable-Synthesis
Copyright
Contents
Preface_2022_Heterogeneous-Catalysis-in-Sustainable-Synthesis
Preface
Chapter-1---Heterogeneous-catalysis-for-organic_2022_Heterogeneous-Catalysis
Heterogeneous catalysis for organic synthesis: Historical background and fundamentals
Introduction and historical background
Catalysis
Fundamentals and basic definitions
Catalyst and catalytic cycle
Activation energy
Other definitions
Heterogeneous catalysis
Catalytic surfaces
Physical and chemical adsorption
The active site of solid catalysts
Anchoring effects
Experimental variables
Catalytic reactors
Conclusions and outlook
References
Chapter-2---Solid-catalysts-for-environm_2022_Heterogeneous-Catalysis-in-Sus
Solid catalysts for environmentally benign synthesis
Introduction
Metal catalysts
Unsupported metals
Bulk or massive metals
Metal “blacks”
Skeletal metals
Noble metal oxides and hydroxides
Amorphous metal alloys
Supported metal catalyst
Catalyst supports
SiO2
Al2O3
Other metal oxides and metal carbonates
Magnetic catalyst supports
Carbon-based supports
Polymeric materials
Biomass-based materials
Self-supported catalysts
Heterogenized metal complexes and organocatalysts
Metal nanoparticle-based catalysts
Nonmetallic catalysts
Metal oxides
Heteropoly acids
Clays
Zeolites
Ion exchange resins
Metal-organic frameworks
Other nonmetallic catalytic materials
Molecular sieves, pillared layer solids, and other mesoporous solids
Composites and related materials
Conclusions and outlook
References
Chapter-3---Application-of-heterogeneous-catalysis_2022_Heterogeneous-Cataly
Application of heterogeneous catalysis in the development of environmentally benign synthetic processes
References
Chapter-3-1---Hydrogenatio_2022_Heterogeneous-Catalysis-in-Sustainable-Synth
Hydrogenation
Introduction
Carbon-carbon multiple bond hydrogenations: Alkenes, alkynes, dienes
Hydrogenation of aromatic and heteroaromatic compounds
Reduction of carbonyl compounds by heterogeneous catalytic hydrogenation: Aldehydes, ketones, and carboxylic acid d ...
Hydrogenation of nitrogen-containing groups: NO, NN, CN, and CN groups
Hydrogenation of the nitro group
Hydrogenation of nitriles
Hydrogenation of imines
Hydrogenation of azides
Chemo- and regioselective hydrogenation of compounds with multiple hydrogenation sensitive groups
Selective CC bond hydrogenation of α,β-unsaturated carbonyl compounds
Selective CO reduction of α,β-unsaturated carbonyl compounds
Complete hydrogenation of multiple functional groups using the same catalytic system
Heterogeneous catalytic hydrogenations by nonconventional activation methods
Microwave-assisted hydrogenations
Ultrasound-assisted hydrogenations
Conclusions and outlook
References
Chapter-3-10---Asymmetric-synthesis-by_2022_Heterogeneous-Catalysis-in-Susta
Asymmetric synthesis by solid catalysts
Introduction
Oxidation reactions
Epoxidation
Dihydroxylation
Other oxidations
Hydrogenation
Reduction of carbonyl compounds
Reduction of mono-carbonyl compounds
Reduction of 1,2-dicarbonyl compounds
Reduction of 1,3-dicarbonyl compounds
Reductive alkylation
Reduction of CC double bonds
Aldol-reaction and related chemistry
Aldol reactions
Michael additions
Henry reactions
Multicomponent and various other reactions
Multicomponent reactions
Cascade and tandem reactions
Other reactions
Conclusions and outlook
References
Chapter-3-2---Heterogeneous-catalytic-hydro_2022_Heterogeneous-Catalysis-in-
Heterogeneous catalytic hydrogenolysis of organic compounds
Introduction
CC bonds
CO bonds
CN bonds
C-halogen bonds—Dehalogenation
NN and NO bonds
CS bonds
Hydrogenolysis of C-other elements (Si, metals) bonds
Hydrogenolysis of biomass-related compounds
Hydrogenolysis of biomass-derived oxygen-containing heterocycles
Hydrogenolysis of biomass-derived other oxygen-containing compounds
Conclusions and outlook
References
Chapter-3-3---Heterogeneous-catalyt_2022_Heterogeneous-Catalysis-in-Sustaina
Heterogeneous catalytic oxidations
Introduction
Epoxidation reactions
Dihydroxylation reactions
Dihydroxylations with osmium
Dihydroxylations with metals other than osmium
Wacker-type oxidation reactions
Oxidative cleavage of hydrocarbons
Cleavage to generate aldehydes and ketones
Cleavage to generate carboxylic acids and esters
Other oxidative cleavage reactions
Oxidation of CO and CN bonds
Oxidation of CO bonds
Oxidation of CN bonds
Dehydrogenation and aromatization of CC and CX bonds
Conclusions and outlook
References
Chapter-3-4---Metathesis-by-heterogen_2022_Heterogeneous-Catalysis-in-Sustai
Metathesis by heterogeneous catalysts
Introduction
Cross-metathesis
Ring-closing metathesis
Ring-opening metathesis
Alkyne metathesis
Heterogeneous catalytic asymmetric metathesis
Metathesis applied to bioderived alkenes
Conclusions and outlook
References
Chapter-3-5---Friedel-Crafts-and-related-re_2022_Heterogeneous-Catalysis-in-
Friedel-Crafts and related reactions catalyzed by solid acids
Introduction
Alkylation, hydroxyalkylation
Alkylations with hydrocarbons
Alkylations with alcohols, ethers, aldehydes, and ketones
Alkylations with alkyl halides
Hydroxyalkylations
Intramolecular transalkylations—Rearrangements
Acylation
Acylations with carboxylic acids
Acylations with activated carboxylic acid derivatives
Intramolecular transacylations—Rearrangements
Friedel-Crafts cycliacyalkylations
Halogenation
Nitration
Sulfonation
Conclusions and outlook
References
Chapter-3-6---Cross-coupling-reactions-for-_2022_Heterogeneous-Catalysis-in-
Cross-coupling reactions for environmentally benign synthesis
Introduction
The Heck coupling
Heck reactions using a heterogeneous catalyst in solution
Solvent-free Heck reactions
Heck reactions without palladium
The Suzuki coupling
Palladium-catalyzed heterogeneous Suzuki coupling reactions
Palladium-free heterogeneous catalytic Suzuki coupling reactions
The Hiyama coupling
The Negishi coupling
The Kumada coupling
The Sonogashira coupling
The Tsuji-Trost allylation
Coupling reactions not involving a C  C bond formation
C  N bond-forming reactions
C  O bond-forming reactions
C  S bond-forming reactions
Conclusions and outlook
References
Chapter-3-7---Multicomponent-re_2022_Heterogeneous-Catalysis-in-Sustainable-
Multicomponent reactions
Introduction
Carbonyl-based multicomponent reactions
Formation of 6-membered rings with multicomponent reactions
Formation of 5-membered rings with multicomponent reactions
Formation of aliphatic bonds
Isocyanide-based reactions
Isocyanide-based MCRs for the preparation of 5-membered rings
Isocyanide-based MCRs for the preparation of 5- and 6-membered heterocycles
Aliphatic bond formation
Conclusions and outlook
References
Chapter-3-8---Ring-transformations-by-he_2022_Heterogeneous-Catalysis-in-Sus
Ring transformations by heterogeneous catalysis
Introduction
Cyclization
Intermolecular cyclization reactions
Diels-Alder and hetero-Diels-Alder reactions
Heterogeneous catalytic synthesis of six-membered rings
Pyrazines and piperazines
Pyridines
Tetrahydropyranols
Heterogeneous catalytic synthesis of five-membered rings
Pyrroles
Furans
The Huisgen 1,3-dipolar cycloaddition
Application of phenylenediamines and/or diazotization
Oxazolidinones/oxindoles
Pyrazoles
Intramolecular cyclization reactions
Heterogeneous catalytic synthesis of five-membered rings
The Nazarov cyclization
Tetrahydrofurans
Heterogeneous catalytic synthesis of six-membered rings
Isopulegol
Ionones
Terpenoids
Quinolines/isoquinolines
Ring opening reactions
Ring opening of small heterocycles
Ring opening of epoxides
Synthesis of β-substituted alcohols
Synthesis of carbonyl compounds
Synthesis of cyclic carbonates
Ring opening of aziridines
Ring opening polymerization
Other types of ring opening reactions
Conclusions and outlook
References
Chapter-3-9---Heterogeneous-catalytic-rearra_2022_Heterogeneous-Catalysis-in
Heterogeneous catalytic rearrangements and other transformations
Rearrangements
Beckmann rearrangement
Fries rearrangement
Epoxide rearrangements
Ferrier rearrangement
Johnson-Claisen rearrangement
The ortho-Claisen-rearrangement
Benzylimine-benzaldimine rearrangement
Pinacol rearrangement
Baeyer-Villiger oxidation
Aldol and related reactions
The aldol reaction
Mukaiyama reaction
Condensations
Schiff-base formation
Knoevenagel condensation
Pechmann condensation
Aldol condensation
Hydrolysis
Hydrolysis of cellulose
Introduction and removal of protecting groups
Hydroformylations
Conclusions and outlook
References
Index_2022_Heterogeneous-Catalysis-in-Sustainable-Synthesis
Index
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D
E
F
G
H
I
J
K
L
M
N
O
P
Q
R
S
T
U
V
W
X
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