دانلود کتاب Nanostructured Materials for Visible Light Photocatalysis (Micro and Nano Technologies)

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Front-Matter_2022_Nanostructured-Materials-for-Visible-Light-Photocatalysis
Front Matter
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Contents
Contributors_2022_Nanostructured-Materials-for-Visible-Light-Photocatalysis
Contributors
1---Fundamentals-principle-of-p_2022_Nanostructured-Materials-for-Visible-Li
Fundamentals principle of photocatalysis
Introduction
Basic principle for photocatalytic reactions
Direct photocatalytic principle
Indirect photocatalytic principle
Reaction pathways for photogenerated electron-hole pair
Pathways of PEHP within a semiconducting catalyst
Charge carrier trapping
Fundamental principles based on the type of catalyst
Semiconductor-based photocatalyst
Quantum dot-based photocatalyst
Two-dimensional material-based photocatalyst
Factors affecting the photocatalysis reaction
Effect of quantity of catalyst
Effect of wavelength and intensity of light
Effect of pH
Effect of the initial concentration of dye
Effect of temperature
Effect of additives
Quantum size effects
Effect of other parameters on the photoactivity of catalyst
Strategies for enhancement of photocatalytic properties of semiconducting materials
Semiconductor-semiconductor heterojunction (Sc-Sc H)
Semiconductor-metal heterojunction (Sc-M H)
Semiconductor-carbon heterojunction (Sc-C H)
Multicomponent heterojunction (McH)
Conclusion
References
2---Nanomaterials-aspects-for-p_2022_Nanostructured-Materials-for-Visible-Li
Nanomaterials aspects for photocatalysis
Introduction to nanomaterials and photocatalysis
Mechanism of photocatalysis
Influence of different parameters on photocatalysis
Catalyst loading
Surface area and morphology
Effect of pH
Effect of temperature
Effect of contaminants concentration
Effect of calcination temperature
Structured photocatalysts for removal of contaminants under visible light
Visible light-active noble metal catalysts
Structured TiO2 photocatalyst and its modifications under visible light
Cation-doped semiconductor photocatalyst
Anion-doped semiconductor photocatalysts
Codoping semiconductor
Self-doping/defect engineering
ZnO and its modifications
TiO2- and ZnO-based heterostructure photocatalysts
Non-TiO2- and ZnO-based new visible light-active catalysts
Ag3PO4 photocatalysts
BiVO4 photocatalyst
WO3 photocatalyst
Summary
References
3---Synthesis-methods-of-nanomaterials-_2022_Nanostructured-Materials-for-Vi
Synthesis methods of nanomaterials for visible light photocatalysis
Introduction
Synthesis methods
Synthesis of Nanopowders
Precipitation method
Coprecipitation method
Sol-gel method
Hydrothermal/solvothermal method
Solid-state reactions
Combustion reactions
Spray pyrolysis
Flame synthesis
Electrospinning method
Chemical vapor deposition
Microwave assisted
Sonochemical method
Microemulsion method
Fabrication of thin films
Electrophoretic deposition
Spin coating method
Spray pyrolysis deposition
Sputtering
Thermal evaporation
Dip-coating method
Doctor blade method
Drop-coating method
Hybrid methods
Conclusion
References
4---Carbon-based-materials-for-visib_2022_Nanostructured-Materials-for-Visib
Carbon-based materials for visible light photocatalysis
Introduction
Carbon-based materials
Carbon nanotubes (CNTs)
Synthesis process of carbon nanotubes (CNTs)
Electric arc discharge
Laser ablation method
Chemical vapor deposition (CVD)
Electrolysis
Carbon dots (CDs)
Graphitic carbon nitride (g-C3N4)
Graphene
N-doped carbon-based materials
P, S-codoped carbon materials
B-doped carbon materials
Photocatalytic reduction of CO2
Photocatalytic removal of NOx
Photocatalytic degradation of organic pollutants
Conclusions and future scopes
References
5---Bismuth-series-photocatalytic-materials_2022_Nanostructured-Materials-fo
Bismuth series photocatalytic materials for the treatment of environmental pollutants
Introduction
Bi-based nanostructured materials synthesis
Synthesis of bismuth oxyhalide
Synthesis of bismuth oxide
Synthesis of other bismuth-based oxides (BiaAOb; A=Fe, V, W, Mo)
Bi-based nanostructured materials for environmental remediation
Photocatalytic degradation of organic pollutants using Bi-based nanostructured materials
Photocatalytic reduction of heavy metals using Bi-based nanostructured materials
Photocatalytic oxidation of air contaminants using Bi-based nanostructured materials
Conclusions and perspectives
References
6---Transition-metal-oxide-based-materia_2022_Nanostructured-Materials-for-V
Transition metal oxide-based materials for visible-light-photocatalysis
Introduction
Different approaches for visible light photocatalysis in TMOs
Doping
Doping in TiO2
Doping in ZnO
Semiconductor heterojunction photocatalysts
Modification by noble metal nanoparticles
Au/TMO-based plasmonic photocatalysts
Ag/TMO-based plasmonic photocatalysts
Dye sensitization
Other TMOs for visible light photocatalysis
Unitary TMOs as visible light photocatalysts (MnO2, Fe2O3, CuxO, WO3)
Conclusion
References
7---Chalcogenides-for-visible-light-_2022_Nanostructured-Materials-for-Visib
Chalcogenides for visible light-induced photocatalysis
Introduction
Classification of chalcogenides
Classification of chalcogenides based on metals
Alkali metal and alkaline earth metal chalcogenides
Transition metal chalcogenides
Monochalcogenides
Dichalcogenides
Tri- and tetrachalcogenides
Metal-rich chalcogenides
Main group chalcogenides
Classification of chalcogenides based on number of elements
Binary chalcogenide
Ternary chalcogenide
Quaternary chalcogenide
Chemistry of metal chalcogenides
Light-active chalcogenide materials
Photocatalytic activity of sulfide, selenide, and telluride
Metal sulfides as photocatalyst chalcogenides
Metal selenides as photocatalyst chalcogenides
Properties of selenide-based chalcogenide: Cadmium selenide
Properties of selenide-based chalcogenides: Nickel selenide
Metal tellurides as photocatalyst chalcogenides
Bandgap energy of cadmium telluride
For an indirect bandgap
For a direct bandgap
Conclusion
References
8---Phosphides-and-nitrides-for-visi_2022_Nanostructured-Materials-for-Visib
Phosphides and nitrides for visible light photocatalysis
Introduction
Background
Basic fundamentals of photocatalysis
Semiconductor materials for photocatalysis
The past and present of photocatalysis
Evolution of phosphides and nitrides for visible light photocatalysis
Phosphides and nitrides
A brief introduction
Phosphides
Nitrides
Synthetic routes for preparation of phosphides and nitrides
Synthesis of phosphides
Synthesis of nitrides
Mechanistic pathway proposal
Role of phosphide
Role of nitride and oxynitride
Challenges and future perspective
Conclusion
References
9---Rare-earth-doped-nanomaterials-for-visibl_2022_Nanostructured-Materials-
Rare earth doped nanomaterials for visible-light-driven photocatalytic degradation of organic dyes
Introduction
Modifications to conventional semiconductors
Nonmetal doping
Transition metal doping
Multiatom doped TiO2
Doping with iron
Coupling with other narrow bandgap semiconductors
Dye sensitization in photocatalysis
Rare earth ions doping
Fluorescence and phosphorescence mechanism
Upconversion luminescent materials
Downconversion phosphors photocatalysis
Long afterglow phosphors (LAPs) Photocatalysis
Conclusion
References
10---Doped-ceramics-for-visible-li_2022_Nanostructured-Materials-for-Visible
Doped ceramics for visible light photocatalysis
Introduction
Doping in ceramics and its influence
Modifications in light absorption
Modifications in the band position
Modification in carrier recombination
Degradation of organic pollutants
Conclusion and future prospects
References
11---Nanocomposites-for-visible-li_2022_Nanostructured-Materials-for-Visible
Nanocomposites for visible light photocatalysis
Introduction
The critical conditions to design heterostructure
Types of heterojunction nanocomposites based on band alignment
Classifications of nanocomposites based on morphology
Synthesis strategies of nanocomposites
Deposition-precipitation method
Hydrothermal and solvothermal method
Ion exchange method
Self-assembly method
Wet impregnation method
Mechanical agitation method
Visible light-driven photocatalytic applications of nanocomposites
Common organic pollutants in wastewater
Photocatalytic dye removal
Emerging pollutants
Photocatalytic degradation of inorganic pollutants
Photocatalytic mechanism
Determination of valence band and conduction band position
Determination of charge carrier separation and transfer
Photoluminescence (PL) spectra, PL study, and lifetime
Transient photocurrent
Electrochemical impedance spectroscopy (EIS)
Determination of reactive species in Photocatalysis
Scavenger study
Electron spin resonance study (ESR)
Conclusion, current challenges, and future prospects
Acknowledgments
References
12---Defects-in-nanomaterials-for-vis_2022_Nanostructured-Materials-for-Visi
Defects in nanomaterials for visible light photocatalysis
Introduction
Classification and type of defects in nanomaterials
Bulk defects
Anion vacancy or oxygen vacancy defects
Cation vacancy or metal (Mn+) vacancy defects
Surface defects
Interface defects
Vacancy associates
Voids or pits and lattice dislocations
Characterization techniques of defects
Spectroscopic techniques
Electron paramagnetic resonance
X-ray photoelectron spectroscopy
Positron annihilation spectroscopy
Photoluminescence (PL) spectroscopy
Microscopic techniques
Conclusion
References
13---Facet-dependent-nanostructures-for_2022_Nanostructured-Materials-for-Vi
Facet-dependent nanostructures for visible light photocatalysis
Introduction
Cuprous oxide photocatalysts
Bismuth vanadates (BiVO4) photocatalyst
Conclusions
References
14---Morphology-dependent-visible-l_2022_Nanostructured-Materials-for-Visibl
Morphology-dependent visible light photocatalysis
Introduction
General mechanism of photocatalysis
Morphology
Zero-dimensional (0D) nanostructures
One-dimensional (1D) nanostructures
Two-dimensional (2D) nanostructures
Three-dimensional (3D) nanostructures
Types of photocatalysts
Single-material photocatalysts
Heterojunction photocatalysts
Common heterojunction photocatalysts
Z-scheme photocatalysts
Plasmonic photocatalysts
Challenges in visible light photocatalysis and advantages of hierarchical photocatalysts
Morphology-dependent visible light photocatalysis for environmental and energy issues
Photodegradation
Photocatalytic water splitting for H2 fuel generation
Photocatalytic CO2 reduction
Future scope
Conclusion
References
15---Green-technology-for-environmen_2022_Nanostructured-Materials-for-Visib
Green technology for environmental hazard remediation
What is green technology?
Principles of sustainability
Benefits from green technologies
Disadvantages of green technologies
Exploring the goals of green technology
Green technology using photocatalysts
Green nanostructured photocatalysts
Principles and mechanisms of green photocatalysis
Sunlight-driven photocatalysts
Metal oxide-driven photocatalysts
Metal-doped metal oxide photocatalysts
Plasmonic photocatalysis
Carbon family photocatalysts
Z-scheme in photocatalysis
Leaf-driven photocatalysis for nanoparticles
Summary
References
16---Degradation-of-emergent-pollutants-us_2022_Nanostructured-Materials-for
Degradation of emergent pollutants using visible light-triggered photocatalysts
Introduction
Emerging pollutants
Visible light-triggered degradation of emerging pollutants
Plasticizers
Agrochemicals
Pharmaceuticals and personal care products (PPCPs)
Food additives and sweeteners
Summary and future outlook
References
17---Agricultural-application-of-vis_2022_Nanostructured-Materials-for-Visib
Agricultural application of visible light photocatalyst
Introduction
Consumption and production of pesticides
Pernicious effects of pesticides
Impact on humans
Impact on biodiversity
Soil pollution
Kind and decomposition of pesticides
Dichlorodiphenyltrichloroethane
Endosulfan
Chlordane
Endrin
Heptachlor
Factors in the photocatalytic activities
pH influence
Intensity of light
Flow rate of feed
Concentration of pollutants
Number of catalyst loading layers
Immobilization temperature of the catalyst layer
Species of ions
Development of photocatalyst under visible light irradiation
Hybrid photocatalysts
Graphene-based photocatalytic composites
TiO2-supported activated carbon composites
Doped-photocatalyst nanoparticles
Other photocatalytic-hybrid materials
Summary
Present and future scope
References
18---Polymer-based-materials-for-visi_2022_Nanostructured-Materials-for-Visi
Polymer-based materials for visible light photocatalysis
Introduction
An overview of recent developed UV- and visible light-induced photocatalysts
Polymer-based photocatalytic materials as efficient photocatalysts
Synthesis and characterization of polymer-based photocatalytic materials
Poly(diacetylene)-based photocatalyst
Characterization of the material
Photocatalytic activity measurements
Polyaniline-based photocatalyst
Polythiophene-based photocatalyst
Polypyrrole-based photocatalysts
Application of polymer-based materials in visible light-induced photocatalysis
Hydrogen production from water under visible light
Degradation of organic pollutants
Degradation of inorganic pollutants
Degradation of biological pollutants
Conclusions and future perspectives
References
19---Large-scale-materials-for-visib_2022_Nanostructured-Materials-for-Visib
Large-scale materials for visible light photocatalysis
Introduction
Strategies for fabrication of photocatalysts on a large scale
Hydrothermal method
Solvothermal method
Thermal method
Wet chemical method
Other synthetic strategies
Applications of large-scale produced photocatalysts
Degradation of pollutants
Removal of toxic gases
Production of hydrogen
Other applications
Photocatalysts synthesized so far on a large scale
Titania-based photocatalysts
Graphitic carbon nitride-based photocatalysts
ZnO-based photocatalysts
Other large-scale synthesized photocatalysts
Summary and future perspective
Acknowledgment
References
20---Industrial-problems-and-solution-to_2022_Nanostructured-Materials-for-V
Industrial problems and solution towards visible light photocatalysis
Introduction
Photocatalysis and its importance
Types of industrial dyes
Photocatalysis mechanism
Light absorption for the generation of electron-hole pairs
Separation of the excited charges
Electron and hole transportation to the surface of the photocatalyst
The redox reaction on the surface
Basic requirements for photocatalysis
Classification of photocatalysts
First-generation photocatalysts
Second-generation photocatalysts
Third-generation photocatalysts
Industrial problems
Advancements and solutions
Summary
References
21---Current-status--research-gaps--and-future_2022_Nanostructured-Materials
Current status, research gaps, and future scope for nanomaterials toward visible light photocatalysis
Introduction
Fundamentals and application areas of photocatalysts
Basic concepts
Application areas of photocatalysts
Water splitting
CO2 reduction
Pollutant removal
Current trends of photocatalysts
Photo(electro)catalyst reactors
Photocatalyst efficiency
Modification of photocatalysts
Heterojunction interface engineering
Z-scheme interfacing
Plasmonic photocatalysts
Metal/nonmetal-doping and sensitizers
Nonmetallic-based photocatalysts
Photoelectrochemistry
Mimicking nature
Summary and future scope
Acknowledgments
References
Index_2022_Nanostructured-Materials-for-Visible-Light-Photocatalysis
Index
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C
D
E
F
G
H
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K
L
M
N
O
P
Q
R
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