توضیحاتی در مورد کتاب :
اثر سرریز یکی از عوامل امیدوارکننده در افزایش سرعت واکنش کاتالیزوری است. پدیده سرریز در دهه 1960 توسط چندین گروه تحقیقاتی مستقل پیدا شد. در سمپوزیوم بینالمللی قبلی در مورد سرریز به صورت زیر تعریف شد: «سرریز شامل انتقال گونههای فعالی است که در فاز اول جذب یا تشکیل میشوند به فاز دیگری که گونهها را تحت شرایط مشابه جذب یا تشکیل نمیدهند». با این حال، این اثر معمولاً در حالت دینامیکی ظاهر می شود، یعنی در طی واکنش هایی که با سرعت واکنش قابل توجهی پیش می روند. این امر روشن کردن اثر سرریز از طریق روشهای استاتیک را دشوار میکند. بنابراین بررسی های اساسی تری ضروری است. توسعه منابع انرژی جایگزین و حفاظت از محیط زیست نیازمند واکنشهای کاتالیزوری بسیار انتخابی و بسیار سریع در شرایط انحرافی است. برای دستیابی به این اهداف به مفاهیم جدیدی مانند اثر سرریز نیاز است. این کتاب شامل 80 مقاله است که شامل روشهایی برای تهیه کاتالیزور به منظور تحقق اثرات سرریز است و محتملترین مکانیسمها را برای توضیح این پدیدههای غیرخطی پیشنهاد میکند. همچنین شامل مطالعاتی در مورد کاربردهای اثر سرریز برای بهبود فرآیندهای کاتالیزوری صنعتی است. این کتاب در توسعه کاتالیزورهای صنعتی و حل مشکلات انرژی و حفاظت از محیط زیست ارزشمند خواهد بود.
فهرست مطالب :
Content:
Edited by
Page iii
Copyright page
Page iv
Preface
Page v
Tomoyuki Inui, Kaoru Fujimoto, Toshio Uchijima, Mitsuo Masai
Organization: Organizing Committee
Page vi
The control of selectivity and stability of catalysts by spillover processes Original Research Article
Pages 1-8
Bernard Delmon
Catalyst design based on spillover theory Original Research Article
Pages 9-16
Kaoru Fujimoto
Spillover effect as the key concept for realizing rapid catalytic reactions Original Research Article
Pages 17-26
T. Inui
The history and perspectives of spillover Original Research Article
Pages 27-43
S.J. Teichner
Synergism in the catalysis of supported gold Original Research Article
Pages 45-52
M. Haruta, S. Tsubota, A. Ueda, H. Sakurai
The effect of spillover hydrogen on coke formation catalyzed by HY zeolite and pillared montmorillonite Original Research Article
Pages 53-60
E. Kikuchi, T. Matsuda
Spectroscopic insight into spillover Original Research Article
Pages 61-68
Wm. Curtis Conner Jr.
Molecular hydrogen-originated solid acid catalysts Original Research Article
Pages 69-76
Hideshi Hattori
Hydrocracking of residual oils with iron supported zeolite containing catalyst Original Research Article
Pages 77-84
Ikusei Nakamura, Ryuichiro Iwamoto, Akira I-ino
Attempt at the characterization of spillover adsorbed species during catalysis
Pages 85-93
Oxygen spillover for the design of industrial oxidation catalysts Original Research Article
Pages 95-103
Yoshihiko Moro-Oka
Surface-to-bulk spillover of hydrogen (proton) in the catalysis of solid heteropoly compounds Original Research Article
Pages 105-110
Makoto Misono, Hiroshi Igarashi, Koichi Katamura, Toshio Okuhara, Noritaka Mizuno
Ion spillover as the origin of the NEMCA effect Original Research Article
Pages 111-116
C.G. Vayenas, S. Bebelis, I.V. Yentekakis, S. Neophytides, Jiang Yi
Reduction of nitrous oxide by electrochemically-generated spillover hydrogen Original Research Article
Pages 117-123
Kiyoshi Otsuka, Hideaki Yamagata
Hydrogen spillover on bimetallic supported Pt-Re particles Original Research Article
Pages 125-130
Do Trong On, Michel Che, Laurent Bonneviot
The role of irreversible and reversible spillover hydrogen in reforming reactions Original Research Article
Pages 131-136
Songying Chen, Yuhan Sun, Shaoyi Peng
New experimental evidence of the long distance hydrogen back spillover (LD-HBS) mechanism in the paraffins aromatization on Zn and Ga ZSM catalysts Original Research Article
Pages 137-142
Gr. Pop, D. Ivanescu, R. Ganea
Hydrogen back spillover phenomena in the aromatization of light alkanes over hybrid catalysts. Mechanistic considerations Original Research Article
Pages 143-149
Raymond Le Van Mao, Jianhua Yao, Louise Dufresne, Riccardo Carli, Vittorio Ragaini
Hydrogen spillover in the conversion of cyclohexane on ZSM-5 zeolites Original Research Article
Pages 151-158
F. Roessner, U. Mroczek, A. Hagen
New active sltes induced by hydrogen spillover in reduced Pt-Ga/HZSM-5 aromatization catalysts Original Research Article
Pages 159-164
E.S. Shpiro, D.P. Shevchenko, R.V. Dmitriev, O.P. Tkachenko, Kh.M. Minachev
Hydroisomerization of n-pentane over hybrid catalysts containing supported hydrogenation catalyst Original Research Article
Pages 165-169
Kohjiroh Aimoto, Kaoru Fujimoto, Ken Maeda
The role of spillover in the hydrogenation of oxygenates adsorbed on Ni/Al2O3 Original Research Article
Pages 171-175
Baoshu Chen, John L. Falconer
Hydrogenation active sites of molybdenum sulfide catalysts enhanced by Ni and Co organometallics Original Research Article
Pages 177-182
Akio Nishijima, Suehiko Yoshitomi, Toshio Sato, Yuji Yoshimura, Hiromichi Shimada, Nobuyuki Matsubayashi
Electrical conductivity study of hydrogen spillover on TiO2 Original Research Article
Pages 183-188
Th. Braunschweig, U. Roland, H. Winkler
Direct observation of surface mobility with microscopic techniques Photoemission electron- and field electron microscopy Original Research Article
Pages 189-194
J.H. Block, M. Ehsasi, V. Gorodetskii, A. Karpowicz, M. Berdau
Selective hydrogen permeation through metal-dispersed porous alumina membrane Original Research Article
Pages 195-200
K. Eguchi, M.-R. Chai, Y. Yamashita, M. Machida, H. Arai
Surface migration of oxygen and of hydrogen in supported metal catalysts Original Research Article
Pages 201-206
D. Martin, D. Duprez
Catalysis and spillover Original Research Article
Pages 207-212
E.P.S. Barrett, A.J. Blackburn, M.A. Yates, Y. Wang, P.A. Sermon
Oxidative conversion of methane on Cu and Ag-NI electrodes at artificial unsteady-state mode of the SOFC reactor operation Original Research Article
Pages 213-216
V.D. Belyaev, V.A. Sobyanin, O.A. Marína
Spillover of atomic oxygen and reverse spillover of dioxygen species on Pt/CeO2 catalyst Original Research Article
Pages 217-222
Can Li, Yanxin Chen, Wenzhao Li, Qin Xin
Methoxy formation/spillover on Pd/Al2O3 studied by 13C, 1H NMR Original Research Article
Pages 223-228
Oc Hee Han, Gustavo Larsen, Kurt W. Zilm, Gary L. Haller
A surface structure model with allowance for spillover Original Research Article
Pages 229-234
R.K. Edvinsson, R.R. Hudgins, P.L. Silveston
A mathematical model for spillover Original Research Article
Pages 235-240
Y.W. Nam, P.L. Silveston
Promoting effect and hydrogen spillover in supported SeRh6-cluster catalysts Original Research Article
Pages 241-246
Y. Izumi, Y. Iwasawa
Heterogeneous catalytic ammoximation of cyclohexanone with ammonia and molecular oxygen Original Research Article
Pages 247-252
G. Busca, E. Giamello, D. Pinelli, F. Trifirò
CO chemisorption and CO-TPR in H2 stream with Rh/NaY and Rh-Zn/NaY zeolite catalysts Original Research Article
Pages 253-256
Y.-D. Xu, A.-M. Liu, D.-M. Li, J.-S. Huang, L. Huang
Plasma-induced chemisorption of nitrogen and hydrogen on alumina-supported platinum catalysts Original Research Article
Pages 257-260
S. Kameoka, S. Ito, K. Kunimori
Characterization of palladium catalyst supported on zeolite Original Research Article
Pages 261-264
Tokuo Matsuzaki, Koji Abe, Kyoji Ohdan, Shuji Tanaka, Keigo Nishihira, Asumaru Nakamura
Surface treatments of silica support for nickel catalyst: effects on hydrogen adsorption/desorption and ethane hydrogenolysis Original Research Article
Pages 265-268
M. Arai, K. Suzuki, Y. Nishiyama
Coadsorption of CO and NO on Co—Rh cluster—derived bimetallic catalysts and NO spillover phenomenon Original Research Article
Pages 269-272
Q. Xin, Z. Cao, Y.Q. Chen, Y. Chen, H. Zhang, C. Li
IR study of Rh-Sn bimetallic system and spillover of oxygen Original Research Article
Pages 273-276
S. Nishiyama, M. Akcmoto, I. Yamamoto, H. Yanagi, S. Tsuruya, M. Masai
Spillover to form CH3O on Pt/Al2O3 and Pd/La2O3 Original Research Article
Pages 277-280
Raymond L. Flesner, Keith B. Kester, Baoshu Chen, John L. Falconer
Nature of Brönsted-acid sites in Ag3PW12O40 in the presence of hydrogen and reversible interconversion of protons and hydrogen Original Research Article
Pages 281-284
Toshihide Baba, Mamoru Nomura, Yoichi Ohno, Yukiyo Hiroyama, Yoshio One
A new concept of hydrogen storage: a Pt/SO42 -ZrO2 material Original Research Article
Pages 285-288
Tsunehiro Tanaka, Kohki Ebitani, Hideshi Hattori, Satohiro Yoshida
Hydrogenation of isobutylene by spiltover hydrogen from Pt/KA-zeolite to NaY-zeolite Original Research Article
Pages 289-292
S. Ohgoshi, I. Nakamura, Y. wakushima
Influence of support modification on hydrogen spillover in ethylene hydrogenation over Pt/Al2O3 Catalyst Original Research Article
Pages 293-296
Genmin Lu
Hydrogenation of sodium fumarate in the solid phase over fine nickel powder Original Research Article
Pages 297-300
Tadao Harada, Tsutomu Osawa
New active site for CO hydrogenation formed on promoted Rh catalyst by spillover hydrogen Original Research Article
Pages 301-304
H. Kato, T. Mori, M. Nakajima, Y. Mori, T. Hattori, Y. Murakami
Spillover effect for the reducing reaction of CO2 with CH4 over SiO2-supported transition metal catalysts physically mixed with MgO Original Research Article
Pages 305-308
Osamu Takayasu, Naomi Hongo, Ikuya Matsuura
Acceleration of dehydrogenation reactions by hydrogen spillover Original Research Article
Pages 309-312
Hayao Imamura, Yoshihisa Sakata, Susurau Tsuchiya
Carbon-supported dehydrogenation catalysts composed of platinum and ruthenium metals Original Research Article
Pages 313-316
Yuji Ando, Xiaomei Li, Eri Ito, Masaru Yamashita, Yasukazu Saito
Diffusion of oxygen atoms from active sites during the catalytic oxidation of carbon monoxide with oxygen on molybdenum trioxide Original Research Article
Pages 317-320
Yasuo Iizuka
Spillover in catalyses over Co-phthalocyanines supported on titania Original Research Article
Pages 321-324
Isao Mochida, Takaaki Higashiizumi, Youichi Ishihara, Hiroshi Fujitsu
CO oxidation over gold supported on TiO2 Original Research Article
Pages 325-328
S. Tsubota, D. Cunningham, Y. Bando, M. Haruta
Platinum metals-ceria synergism in autoexhaust catalyst Original Research Article
Pages 329-332
T. Yamada, K. Kayano, M. Funabiki
Hysteresis and self-oscillation in a selective catalytic reduction of nitric oxide by hydrocarbons on alumina Original Research Article
Pages 333-336
A. Obuchi, A. Ogata, K. Mizuno, A. Ohi, H. Ohuchi
The effect of electrochemical pumping of oxygen on catalytic behaviour of metal electrodes in methane oxidation Original Research Article
Pages 337-340
O.A. Mar\'ina, V.A. Sobyanin, V.D. Belyaev, V.N. Parmon
Possibility of sulfur spillover on hydrodesulfurization catalysts using radioactive 35S Original Research Article
Pages 341-344
T. Kabe, A. Ishihara, W. Qian, S. Ogawa, H. Sakuno
New evidence of the promotion of activity and selectivity through hydrogen spill-over activation of biphasic sulfided hydrotreating catalysts Original Research Article
Pages 345-348
S. Giraldo de León, P. Grange, B. Delmon
Interaction between Co species and Mo species in C0O-M0O3/AI2o3 Original Research Article
Pages 349-352
Muneyoshi Yamada, Seiji Kasahara, Kan Kawahara
Hydrogen spillover on ruthenium promoted molybdenum catalysts for hydrodesulfurization Original Research Article
Pages 353-356
X.S. Li, Z.S. Hou, Q. Xin
Development of hydrodesulfurization catalysts prepared using metal carbonyls Original Research Article
Pages 357-360
A. Ishihara, M. Nomura, M. Azuma, M. Matsushita, K. Shirouchi, T. Kabe
Transfer hydrocracking of heavy oils with metal-supported carbon catalyst Original Research Article
Pages 361-364
Ikusei Nakamura, Kohjiro Aimoto, Kaoru Fujimoto
Enhancing effect of hydrogen sulfide for cracking of n-hexane over alkali and alkaline earth metal zeolites Original Research Article
Pages 365-368
M. Sugioka, M. Amisawa, K. Sato, H. Abe
Spillover effect in methane reforming reactions on Ni-based composite catalysts modified with precious metals Original Research Article
Pages 369-372
T. Inui, K. Fujioka, W. Tanakulrungsank, T. Takeguchi
Behavior of surface oxygen on a Rh/Si02 catalyst in oxidation of methane Original Research Article
Pages 373-376
J. Nakamura, K. Kubushiro, T. Uchijima
Utilization of oxide ion transfer for oxidative coupling of methane with membrane reactors Original Research Article
Pages 377-380
T. Nozaki, K. Omata, K. Fujimoto
Highly dispersed cobalt catalysts modified with transition metals and their applications to CO hydrogenation Original Research Article
Pages 381-384
Y. Sugi, T. Matsuzaki, H. Arakawa, K. Takeuchi, T. Hanaoka
Continuous catalysis on oxides in the presence of spiltover hydrogen Original Research Article
Pages 385-388
M.S.W. Vong, P.A. Sermon
Promoting effect of Ti02 addition to CuO-ZnO catalyst on methanol synthesis by catalytic hydrogenation of CO2 Original Research Article
Pages 389-392
H. Arakawa, K. Sayama, K. Okabe, A. Murakami
Spillover effect on the stabilization of Cu-Zn catalyst for CO2 hydrogenation to methanol Original Research Article
Pages 393-396
K. Fujimoto, Y. Yu
Hydrogenation of CO2 over metal supported fine particles Original Research Article
Pages 397-400
Takayoshi Uematsu, Masatoshi Fukuda, Tsuyoshi Iijima, Shogo Shimazu
Spillover effects of hydrogen on the reduction of CO2 over supported metal catalysts Original Research Article
Pages 401-404
Toshiaki Sodesawa, Satoshi Sato, Fumio Nozaki
Synergistic effect of Pd and Mn203 in combustion reactions Original Research Article
Pages 405-408
Y. Tsuji, S. Imamura
Catalytic gasification activity of iron enhanced by spilt-over hydrogen Original Research Article
Pages 409-412
Shiro Matsumoto, Sakumitsu Sakagami
Catalytic behavior of iron in the gasification of coal with hydogen Original Research Article
Pages 413-416
Kenji Asami, Yasuo Ohtsuka
Liquid-phase hydroxylation of xylene with hydrogen peroxide over zeolite catalysts Original Research Article
Pages 417-420
T. Yashima, S. Nagase, T. Komatsu, S. Nambab
Promoting effects of noble metals on the detection of ammonia by semiconductor gas sensor Original Research Article
Pages 421-424
Tomoki Maekawa, Jun Tamaki, Norio Miura, Noboru Yamazoe
Manganese oxide and niobium oxide catalysts prepared by a proton exchange and elimination method Original Research Article
Pages 425-428
Y. Inoue, K. Sato, H. Takahashi, S. Yasukawa
Promoting role of metal additives in modified Pd catalysts for selective hydrodechlorination of CFC-113 Original Research Article
Pages 429-432
R. Ohnishi, H. Suzuki, W.-L. Wang, M. Ichikawa
Author Index
Pages 433-435
توضیحاتی در مورد کتاب به زبان اصلی :
The spillover effect is one of the most promising factors in the enhancement of catalytic reaction rates. The spillover phenomenon was found in the 1960s by several researcch groups independently. It was defined at the previous International Symposium on Spillover as follows "Spillover involves the transport of active species which are adsorbed or formed on a first phase onto another phase that does not adsorb or form the species under the same condition". However, this effect appears typically in the dynamic state, i.e., during reactions, which advance with a considerable reaction rate. This makes it difficult to elucidate the spillover effect through static methods. Therefore, more fundamental investigations are necessary. The development of alternative energy sources and protection of the environment demands highly selective and very rapid catalytic reactions at deviating conditions. To achieve these goals new concepts, such as the spillover effect, aree needed. This proceedings book, which comprises 80 papers contains methods for preparing catalysts in order to realize spillover effects and suggests the most probable mechanisms to explain these non-linear phenomena. It also contains studies on applications of the spillover effect to improve industrial catalytic processes. The book will be invaluable in the development of industrial catalysts and for solving energy and environmental protection problems.