دانلود کتاب Organic Chemistry : Structure and Mechanisms.

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Front Cover......Page 1
Contents......Page 6
Introduction......Page 10
1. Mechanistic Aspects of the Isomerization of Z-Vinylic Tellurides Double Bonds in the Synthesis of Potassium Z-Vinyltrifluoroborate Salts......Page 12
2. The Role of Heterogeneous Chemistry of Volatile Organic Compounds: A Modeling and Laboratory Study......Page 20
3. Total Synthesis of the Indolizidine Alkaloid Tashiromine......Page 28
4. Application of Stir Bar Sorptive Extraction to Analysis of Volatile and Semivolatile Organic Chemicals of Potential Concern in Solids and Aqueous Samples from the Hanford Site......Page 38
5. Analogues of Amphibian Alkaloids: Total Synthesis of (5R,8S,8as)-(-)-8-Methyl-5-Pentyloctahydroindolizine (8-Epi-Indolizidine 209B) and [(1S,4R,9as)-(-) -4- Pentyloctahydro-2H-Quinolizin-1-Yl]Methanol......Page 50
6. An Efficient Preparation, Spectroscopic Properties, and Crystal Structure of 1,1-Bis(4-[2-(dimethylamino)ethoxy]phenyl)-2- (3-guaiazulenyl)ethylene......Page 61
7. Characterizing the Formation of Secondary Organic Aerosols......Page 70
8. Combining Two-Directional Synthesis and Tandem Reactions, Part 11: Second Generation Syntheses of (±)-Hippodamine and (±)-Epi-Hippodamine......Page 103
9. Accelerations in the Lactonization of Trimethyl Lock Systems are Due to Proximity Orientation and not to Strain Effects......Page 110
10. Unexpected Degradation of the Bisphosphonate P-C-P Bridge Under Mild Conditions......Page 122
11. Synthesis of Benzo[b]fluorenone Nuclei of Stealthins......Page 130
12. Shape-Persistent Macrocycles with Intraannular Alkyl Groups: Some Structural Limits of Discotic Liquid Crystals with an Inverted Structure......Page 141
13. Part 1. Reduction of S-Alkyl-Thionocarbonates and Related Compounds in the Presence of Trialkylboranes/Air......Page 152
14. Part 2. Mechanistic Aspects of the Reduction of S-Alkyl-Thionocarbonates in the Presence of Triethylborane and Air......Page 162
15. Part 3. Triethylborane-Air: A Suitable Initiator for Intermolecular Radical Additions of S-2-Oxoalkyl-Thionocarbonates (S-Xanthates) to Olefins......Page 172
16. Catalytic Oxidative Cleavage of C=N Bond in the Presence of Zeolite H-NaX Supported Cu(NO3)2, as a Green Reagent......Page 182
17. A Divergent Asymmetric Approach to Aza-Spiropyran Derivative and (1S,8ar)-1-Hydroxyindolizidine......Page 189
18. Flexible Synthesis of Poison-Frog Alkaloids of the 5,8-Disubstituted Indolizidine-Class. II: Synthesis of (-)-209B, (-)-231C, (-)-233D, (-)-235B”, (-)-221I, and an Epimer of 193E and Pharmacological Effects at Neuronal Nicotinic Acetylcholine Receptors......Page 198
19. A Novel, One-Step Palladium and Phenylsilane Activated Amidation from Allyl Ester on Solid Support......Page 208
20. The First Organocatalytic Carbonyl-Ene Reaction: Isomerisation-Free C-C Bond Formations Catalysed By H-Bonding Thio-Ureas......Page 215
21. Synthesis and Biological Evaluation of 7-O-Modified Formononetin Derivatives......Page 222
22. Expedient Syntheses of the N-Heterocyclic Carbene Precursor Imidazolium Salts Ipr·Hcl, Imes·Hcl and Ixy·Hcl......Page 230
23. CS2CO3 /[bmim]Br as an Efficient, Green, and Reusable Catalytic System for the Synthesis of N-Alkyl Derivatives of Phthalimide under Mild Conditions......Page 240
24. Conformational Rigidity of Silicon-Stereogenic Silanes in Asymmetric Catalysis: A Comparative Study......Page 249
25. Photochromism of Dihydroindolizines Part XI: Synthesis of Novel Carbon-Rich Photochromic Dihydroindolizines-Based Potential Electronic Devices......Page 256
26. 8-Epi-Salvinorin B: Crystal Structure and Affinity at the K Opioid Receptor......Page 265
27. Effect of Transannular Interaction on the Redox-Potentials in a Series of Bicyclic Quinones......Page 272
28. Three-Component One-Pot Synthesis of Novel Benzo[b] 1,8-naphthyridines Catalyzed by Bismuth(III) Chloride......Page 286
29. The Vicinal Difluoro Motif: The Synthesis and Conformation of Erythro- and Threo-Diastereoisomers of 1,2-Difluorodiphenylethanes, 2,3-Difluorosuccinic Acids and their Derivatives......Page 294
30. The Influence of Traffic and Wood Combustion on the Stable Isotopic Composition of Carbon Monoxide......Page 316
31. Reduction of Arenediazonium Salts by Tetrakis(Dimethylamino) Ethylene (TDAE): Efficient Formation of Products Derived from Aryl Radicals......Page 348