دانلود کتاب Oxide-Ion Conduction in the Dion–Jacobson-Type Layered Perovskites

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Supervisor’s Foreword
Acknowledgements
Contents
1 Introduction
1.1 Background
1.1.1 Energy and the Environment
1.1.2 Oxide-Ion Conductor
1.1.3 Perovskite and Perovskite-Related Oxides
1.2 Previous Studies
1.2.1 Oxide-Ion Conduction in Perovskite or Perovskite-Related Structures
1.2.2 Properties of Dion–Jacobson-Type Layered Perovskites
1.3 Crystal Structure Analysis
1.3.1 Synchrotron X-ray Powder Diffraction
1.3.2 High-Temperature Synchrotron X-ray Powder Diffraction
1.3.3 Neutron Diffraction
1.3.4 High-Temperature Neutron Diffraction
1.3.5 Rietveld Refinement
1.4 Electrical Properties Measurement
1.4.1 Temperature Dependence of Total Electrical Conductivities
1.4.2 The Oxygen Partial Pressure Dependence of Total Electrical Conductivities
1.4.3 Oxygen Concentration Cell Measurements
1.4.4 Impedance Spectroscopy Measurements
1.5 Bond-Valence-Based Energy Calculation
1.6 Maximum-Entropy Method Analysis
1.7 Density Functional Theory Calculation
References
2 New Oxide-Ion Conductors of Dion–Jacobson-Type Layered Perovskites CsBi2Ti2NbO10-δ
2.1 Introduction
2.2 Experimental Section
2.2.1 Synthesis and Characterization
2.2.2 Electrical Conductivity Measurements
2.2.3 Neutron and Synchrotron X-ray Diffraction Measurements
2.2.4 Bond-Valence-Based Energy Calculation
2.2.5 Maximum-Entropy Method Analysis
2.2.6 Oxygen Concentration-Cell Measurements
2.2.7 Improved Oxide-Ion Conductivity by Doping
2.3 Results and Discussion
2.4 Conclusion
2.5 Outlook
References
3 New Oxide-Ion Conductors of Dion–Jacobson-Type Layered Perovskites CsLn2Ti2NbO10 (Ln = La, Pr, Nd, Sm, Gd, Ho, and Yb) and CsLa2–xMxTi2+yNb1–yO10–x/2–y/2 (M = Ca, Sr, and Ba; x = 0, 0.1; y = 0.1, 0, and –0.1)
3.1 Introduction
3.2 Experimental
3.2.1 Synthesis and Characterization
3.2.2 Electrical Conductivity Measurements
3.2.3 Neutron and Synchrotron X-ray Diffraction Measurements
3.2.4 Density Functional Theory Calculation
3.2.5 Investigation of Oxide-Ion Diffusion Pathways
3.2.6 Improved Oxide-Ion Conductivity by Doping
3.3 Results and Discussion
3.4 Conclusion
References
4 Conclusion and Future Work