دانلود کتاب Pauson-Khand Reaction: Scope, Variations and Applications, The

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The Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce cyclopentenones.   The importance of this reaction originates from its high value in transforming simple components into the synthetically useful cyclopentenone unit, in which a high degree of molecular complexity can be achieved in a single step, with impressive stereochemical and regiochemical control.

The Pauson-Khand Reaction investigates the nature and many variations of this reaction.

Topics covered include: 

• the mechanisms of Pauson?Khand-type reactions
• non chiral  intramolecular and intermolecular versions of Pauson?Khand reactions
• asymmetric Pauson?Khand reaction using chiral auxiliaries
• the enantioselective Pauson?Khand reaction
• Pauson?Khand reactions catalysed by metals other than cobalt
• unconventional Pauson?Khand reactions
• the Pauson?Khand reaction in total synthesis

Presenting a comprehensive overview of this fundamental reaction, The Pauson-Khand Reaction will find a place on the bookshelves of any organic or organometallic chemist. Content:
Chapter 1 The Pauson?Khand Reaction – an Introduction (pages 1–21): William J. Kerr
Chapter 2 The Mechanism of the Pauson?Khand Reaction: Hypothesis, Experimental Facts, and Theoretical Investigations (pages 23–48): Xacobe C. Cambeiro and Miquel A. Pericas
Chapter 3 Non Chiral Pauson?Khand Reaction (pages 49–68): Takanori Shibata
Chapter 4 Diastereoselective Pauson?Khand Reaction using Chiral Pool Techniques (Chiral Substrates) (pages 69–93): Martin Kamlar, Jan Vesely and Ramon Rios Torres
Chapter 5 Asymmetric Intra? and Intermolecular Pauson?Khand Reactions: The Chiral Auxiliary Approach (pages 95–146): Albert Moyano
Chapter 6 The Enantioselective Pauson?Khand Reaction (pages 147–180): Agusti Lledo, Xavier Verdaguer and Antoni Riera
Chapter 7 Recent Advancement of Catalytic Pauson?Khand?type Reactions (pages 181–210): Fuk Loi Lam, Hang Wai Lee, Jun Wang and Fuk Yee Kwong
Chapter 8 Recent Adventures with the Pauson?Khand Reaction in Total Synthesis (pages 211–238): Scott G. Van Ornum, Sarah Hoerner and James M. Cook
Chapter 9 Heterogeneous Catalytic Pauson?Khand Reaction (pages 239–273): Young Keun Chung
Chapter 10 Other Transition Metal?Mediated Cyclizations Leading to Cyclopentenones (pages 275–305): Ramon Rios Torres and Jan Vesely