دانلود کتاب PVC degradation and stabilization

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Front Cover......Page 1
PVCDegradationand Stabilization......Page 2
Table of Contents......Page 4
Copyright Page......Page 3
1.1 Repeat structures and their basic organic chemistry......Page 12
1.2 Molecular weight and its distribution......Page 19
1.3 Prediction of formation of irregular segments......Page 21
1.4 Irregular segments......Page 23
References......Page 32
2.1 Monomer......Page 36
2.2 Basic steps of radical polymerization......Page 38
2.3 Polymerization technology......Page 42
2.4 Polymerization conditions and PVC properties......Page 49
2.5 Optimal operation of Industrial PVC dryer......Page 56
References......Page 57
3.1 Molecular weight of polymer (chain length)......Page 58
3.2 Configuration and conformation......Page 62
3.3 Chain folds......Page 69
3.5 Entanglements......Page 71
3.6 Crystalline structure......Page 74
3.7 Grain morphology......Page 79
References......Page 86
4.1 The reasons for polymer instability......Page 90
4.2 Mechanisms of thermal degradation......Page 114
4.3 Kinetics......Page 124
4.4 Results of thermal degradation......Page 136
4.5 Effect of additives......Page 143
References......Page 169
Chapter 5. Principles of UV Degradation......Page 180
5.1 Reasons for polymer instability......Page 182
5.2 Mechanisms of degradation......Page 190
5.3 Kinetics......Page 198
5.4 Results of UV degradation......Page 201
5.5 Effect of additives......Page 205
References......Page 215
6.2 Mechanisms......Page 218
6.4 Results......Page 220
6.5 Effect of additives......Page 221
References......Page 225
7.1 Argon plasma......Page 228
7.2 β-radiation (electron beam)......Page 229
7.5 Ion (proton) beam......Page 231
7.6 Laser......Page 233
7.8 Microwave......Page 235
7.9 Neutron irradiation......Page 236
7.10 Oxygen plasma......Page 237
7.11 X-rays......Page 238
References......Page 239
Chapter 8. Mechanodegradation......Page 242
References......Page 246
9.1 Methods of chemical dehydrochlorination......Page 248
9.2 Kinetics and mechanisms of reaction......Page 251
References......Page 255
10.1 Heat stability test......Page 258
10.2 Thermogravimetric analysis......Page 267
10.3 Combustion......Page 269
10.4 Optical properties......Page 270
10.5 Spectroscopic methods......Page 272
10.6 Chromatographic methods......Page 284
10.7 Mechanical properties......Page 286
10.8 Morphology......Page 287
10.9 Other essential methods of testing......Page 289
10.10 International standards......Page 291
References......Page 297
11.1 Functions of PVC stabilizers......Page 308
11.2 Theories......Page 320
11.3 Stabilizer groups......Page 332
References......Page 433
12.1 Toxic substance control......Page 442
12.2 Carcinogenic effect......Page 445
12.3 Teratogenic and mutagenic effect......Page 449
12.5 Workplace exposure limits......Page 451
12.6 Exposure from consumer products......Page 454
12.7 Drinking water......Page 455
12.8 Food regulatory acts......Page 457
12.9 Toxicity of stabilizers......Page 462
12.13 Energy recovery......Page 466
References......Page 467
Index......Page 470