دانلود کتاب Supramolecular Chemistry

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Title Page Copyright Page About the Authors Preface to the Third Edition Acknowledgements About the Front Cover About the Companion Website CHAPTER 1: Concepts 1.1 DEFINITION AND DEVELOPMENT OF SUPRAMOLECULAR CHEMISTRY 1.2 CLASSIFICATION OF SUPERMOLECULE FORMATION 1.3 RECEPTORS, COORDINATION, AND THE LOCK AND KEY ANALOGY 1.4 BINDING CONSTANTS 1.5 COOPERATIVITY, MULTIVALENCY, AND THE CHELATE EFFECT 1.6 PREORGANISATION AND COMPLEMENTARITY 1.7 THERMODYNAMIC AND KINETIC SELECTIVITY, AND DISCRIMINATION 1.8 NATURE OF SUPRAMOLECULAR INTERACTIONS 1.9 SOLVATION EFFECTS 1.10 SUPRAMOLECULAR CONCEPTS AND DESIGN 1.11 PRACTICAL APPLICATIONS OF SUPRAMOLECULAR CHEMISTRY SUMMARY STUDY PROBLEMS REFERENCES CHAPTER 2: The Supramolecular Chemistry of Life 2.1 BIOLOGICAL INSPIRATION FOR SUPRAMOLECULAR CHEMISTRY 2.2 ALKALI METAL CATIONS IN BIOCHEMISTRY 2.3 PORPHYRINS AND TETRAPYRROLE MACROCYCLES 2.4 SUPRAMOLECULAR FEATURES OF PLANT PHOTOSYNTHESIS 2.5 UPTAKE AND TRANSPORT OF OXYGEN BY HAEMOGLOBIN 2.6 ENZYMES AND COENZYMES 2.7 SIGNALLING: NEUROTRANSMITTERS, HORMONES, AND PHEROMONES 2.8 DNA AND THE GENETIC CODE 2.9 BIOCHEMICAL SELF‐ASSEMBLY 2.10 BIOMINERALISATION 2.11 EMERGENCE OF LIFE SUMMARY REFERENCES CHAPTER 3: Cation‐Binding Hosts 3.1 INTRODUCTION TO COORDINATION CHEMISTRY 3.2 PODANDS 3.3 THE CROWN AND LARIAT ETHERS 3.4 THE CRYPTANDS 3.5 THE SPHERANDS 3.6 NOMENCLATURE OF CATION‐BINDING MACROCYCLES 3.7 SELECTIVITY OF CATION COMPLEXATION 3.8 SOLUTION BEHAVIOUR AND APPLICATIONS OF CROWNS AND CRYPTANDS 3.9 MACROCYCLE SYNTHESIS: THE TEMPLATE EFFECT AND HIGH DILUTION 3.10 SOFT LIGANDS FOR SOFT METAL IONS 3.11 PROTON BINDING: THE SIMPLEST CATION 3.12 COMPLEXATION OF ORGANIC CATIONS 3.13 ALKALIDES AND ELECTRIDES 3.14 THE CALIXARENES 3.15 CARBON DONOR AND π‐ACID LIGANDS 3.16 THE SIDEROPHORES SUMMARY REFERENCES CHAPTER 4: Anion Binding 4.1 INTRODUCTION 4.2 BIOLOGICAL ANION RECEPTORS 4.3 CONCEPTS IN ANION HOST DESIGN 4.4 CATIONIC RECEPTORS 4.5 NEUTRAL RECEPTORS 4.6 BORON BASED RECEPTORS AND LEWIS ACID CHELATES 4.7 METAL‐CONTAINING RECEPTORS 4.8 ANION‐BINDING HELICES 4.9 ANION TRANSPORT SUMMARY THOUGHT EXPERIMENTS REFERENCES CHAPTER 5: Ion‐Pair Receptors 5.1 SIMULTANEOUS ANION AND CATION BINDING 5.2 LABILE COORDINATION COMPLEXES AND CAGES AS ANION HOSTS 5.3 RECEPTORS FOR ZWITTERIONS SUMMARY STUDY PROBLEMS REFERENCES CHAPTER 6: Molecular Guests in Solution 6.1 MOLECULAR HOSTS AND MOLECULAR GUESTS 6.2 INTRINSIC CURVATURE: GUEST BINDING BY CAVITANDS 6.3 CYCLODEXTRINS 6.4 MOLECULAR TWEEZERS, CLIPS AND CLEFTS 6.5 CYCLOPHANE HOSTS 6.6 CONSTRUCTING A SOLUTION HOST FROM CLATHRATE‐FORMING BUILDING BLOCKS: THE CRYPTOPHANES 6.7 COVALENT CAGES: CARCERANDS AND HEMICARCERANDS 6.8 COORDINATION CAGES 6.9 HALOGEN‐BONDED COMPLEXES SUMMARY STUDY PROBLEMS THOUGHT EXPERIMENT REFERENCES CHAPTER 7: Solid‐State Inclusion Compounds 7.1 NOMENCLATURE AND THERMOCHEMICAL ASPECTS 7.2 POROSITY AND GAS SORPTION 7.3 CLATHRATE HYDRATES 7.4 UREA AND THIOUREA CLATHRATES 7.5 CHANNEL CLATHRATES 7.6 POLARITY FORMATION 7.7 HYDROQUINONE, PHENOL, DIANIN’S COMPOUND, AND THE HEXAHOST STRATEGY 7.8 MACROCYCLIC CLATHRATES 7.9 COVALENT CAGES 7.10 GAS SORPTION BY COORDINATION COMPLEX HOSTS SUMMARY STUDY PROBLEMS REFERENCES CHAPTER 8: Crystal Engineering 8.1 CONCEPTS 8.2 CRYSTAL NUCLEATION AND GROWTH 8.3 UNDERSTANDING CRYSTAL STRUCTURES 8.4 THE CAMBRIDGE STRUCTURAL DATABASE 8.5 POLYMORPHISM 8.6 CO‐CRYSTALS 8.7 SOLID STATE TRANSFORMATIONS 8.8 CRYSTAL STRUCTURE PREDICTION 8.9 COMMON AND EXOTIC SUPRAMOLECULAR SYNTHONS 8.10 HALOGEN BONDING 8.11 BENDING AND JUMPING CRYSTALS SUMMARY STUDY PROBLEMS THOUGHT EXPERIMENT REFERENCES CHAPTER 9: Network Solids 9.1 WHAT ARE NETWORK SOLIDS? 9.2 ZEOLITES 9.3 LAYERED SOLIDS AND INTERCALATES 9.4 IN THE BEGINNING: HOFFMAN INCLUSION COMPOUNDS AND WERNER CLATHRATES 9.5 COORDINATION POLYMERS 9.6 POROUS METAL–ORGANIC FRAMEWORKS 9.7 COVALENT ORGANIC FRAMEWORKS SUMMARY STUDY PROBLEM REFERENCES CHAPTER 10: Self‐Assembly 10.1 INTRODUCTION 10.2 PROTEINS AND FOLDAMERS: SINGLE‐MOLECULE SELF‐ASSEMBLY 10.3 BIOCHEMICAL SELF‐ASSEMBLY 10.4 SELF‐ASSEMBLY IN SYNTHETIC SYSTEMS: KINETIC AND THERMODYNAMIC CONSIDERATIONS 10.5 HELICATES AND HELICAL ASSEMBLIES 10.6 SELF‐ASSEMBLING COORDINATION COMPOUNDS 10.7 SELF‐ASSEMBLY OF CLOSED COMPLEXES BY HYDROGEN BONDING 10.8 TEMPLATED ASSEMBLY OF PORPHYRIN ARRAYS 10.9 PROGRAMMED ASSEMBLY WITH BIOMOLECULES SUMMARY STUDY PROBLEMS THOUGHT EXPERIMENT REFERENCES CHAPTER 11: The Mechanical Bond 11.1 SCOPE AND IMPORTANCE OF MECHANICAL BONDING AND MECHANOSTEREOCHEMISTRY 11.2 CATENANES AND ROTAXANES 11.3 MOLECULAR KNOTS 11.4 BORROMEAN RINGS AND MULTIPLY INTERLOCKED CATENANES 11.5 INTERPENETRATED CAGES 11.6 AN UNUSUAL THRING SUMMARY STUDY PROBLEM REFERENCES CHAPTER 12: Molecular Devices and Machines 12.1 INTRODUCTION 12.2 SUPRAMOLECULAR PHOTOCHEMICAL DEVICES 12.3 INFORMATION AND SIGNALS: SEMIOCHEMISTRY AND SENSING 12.4 MOLECULE‐BASED ELECTRONICS 12.5 MOLECULAR ANALOGUES OF MECHANICAL MACHINES SUMMARY STUDY PROBLEMS REFERENCES CHAPTER 13: Biological Mimics and Supramolecular Catalysis 13.1 INTRODUCTION 13.2 CYCLODEXTRINS AS ENZYME MIMICS 13.3 CORANDS AS ATPASE MIMICS 13.4 CATION‐BINDING HOSTS AS TRANSACYLASE MIMICS 13.5 METALLOBIOSITES 13.6 ENZYME MIMETIC MATERIALS 13.7 ION CHANNEL MIMICS 13.8 SUPRAMOLECULAR CATALYSIS SUMMARY THOUGHT EXPERIMENT REFERENCES CHAPTER 14: Interfaces and Liquid Assemblies 14.1 ORDER IN LIQUIDS 14.2 SURFACTANTS AND INTERFACIAL ORDERING 14.3 LIQUID CRYSTALS 14.4 POLYAMORPHOUS LIQUIDS 14.5 IONIC LIQUIDS AND DEEP EUTECTIC SOLVENTS 14.6 LIQUID CLATHRATES 14.7 POROUS LIQUIDS SUMMARY STUDY PROBLEMS REFERENCES CHAPTER 15: Supramolecular Materials 15.1 INTRODUCTION 15.2 DENDRIMERS 15.3 FRACTAL ASSEMBLIES 15.4 COVALENT POLYMERS WITH SUPRAMOLECULAR PROPERTIES 15.5 SELF‐ASSEMBLED SUPRAMOLECULAR POLYMERS 15.6 MECHANICALLY INTERLOCKED MATERIALS 15.7 SUPRAMOLECULAR GELS 15.8 POLYMERIC LIQUID CRYSTALS 15.9 BIOLOGICAL SELF‐ASSEMBLED MATERIALS SUMMARY STUDY PROBLEMS REFERENCES CHAPTER 16: Dynamic Covalent Bonding and Complex Systems 16.1 CHEMISTRY OUT OF EQUILIBRIUM 16.2 DYNAMIC COMBINATORIAL LIBRARIES 16.3 SELF‐REPLICATION 16.4 SHAPESHIFTING MOLECULES 16.5 DISSIPATIVE SELF‐ASSEMBLY SUMMARY REFERENCES CHAPTER17 Nanochemistry 17.1 WHEN IS NANO REALLY NANO? 17.2 NANOTECHNOLOGY: THE ‘TOP‐DOWN’ AND ‘BOTTOM‐UP’ APPROACHES 17.3 TEMPLATED AND BIOMIMETIC MORPHOSYNTHESIS 17.4 NANOSCALE PHOTONICS 17.5 MICROFABRICATION, NANOFABRICATION AND SOFT LITHOGRAPHY 17.6 ASSEMBLY AND MANIPULATION ON THE NANOSCALE 17.7 NANOPARTICLES 17.8 ENDOHEDRAL FULLERENES, NANOTUBES AND GRAPHENE SUMMARY THOUGHT EXPERIMENT REFERENCES Index End User License Agreement