دانلود کتاب The Cation–π Interaction

فهرست مطالب :

Preface
Contents
1 Introduction
1.1 Non-covalent Interaction
1.2 Cation–π Interaction
References
2 Fundamentals of Cation–π Interactions
2.1 Metal Ions
2.1.1 Alkali Metal Ions
2.1.2 Alkaline Earth Metal Ions
2.1.3 Transition Metal Ions
2.2 Organic Cations
2.2.1 Structural Diversity
2.2.2 Pyridinium Ions
2.2.3 Quaternary Ammonium Ions
2.2.4 Guanidinium Ions
2.3 π-Systems
2.3.1 Aromatic Rings
2.3.2 Alkenes and Alkynes
2.3.3 Carbonyl and Thiocarbonyl Groups
2.4 Factors Affecting Interactions
2.4.1 Solvent Effect
2.4.2 Counter-Anion Effect
2.4.3 Directional Dependence
2.5 Cooperation Among Non-covalent Interactions
2.5.1 Ternary Systems
2.5.2 Multiple Systems
2.5.3 Cooperation with Hydrogen Bonds
2.5.4 Cooperation with Halogen Bonds
References
3 Biological Systems
3.1 Protein Structure
3.1.1 PDB Analysis of Protein Structures
3.1.2 α-Helix
3.1.3 β-Hairpin
3.1.4 Miniature Proteins
3.1.5 pH Dependence on Protein Conformation
3.2 Protein–Protein Association
3.2.1 PDB Analysis of Protein–Protein Interfaces
3.2.2 Helix–Helix Association
3.2.3 Self-Assembly of Collagen-Mimetic Peptides
3.2.4 Dissociation of UVR8 Homodimer
3.3 Protein–DNA Association
3.3.1 PDB Analysis of Protein–DNA Complexes
3.3.2 Nuclear Cap-Binding Complexes
3.4 Protein–Ligand Association
3.4.1 Recognition of Quaternary Ammonium Ions
3.4.2 Biosynthesis of Aristolochene
3.4.3 Cellulase–Lignin Association
3.4.4 Recognition of Purine Analogues
3.5 Ion Channels
3.5.1 Ligand-Gated Ion Channels
3.5.2 Voltage-Gated Ion Channels
References
4 Organic Synthesis
4.1 Role of Cation–π Interactions in Organic Reactions
4.2 Organic Cations
4.2.1 Pyridinium and Heteroaromatic Cations
4.2.2 Iminium Ions
4.2.3 Oxonium Ions
4.2.4 Carbocations
4.2.5 Quaternary Ammonium Ions
4.3 Alkali Metal Ions
4.3.1 Lithium Ion
4.3.2 Sodium Ion
4.3.3 Potassium Ion
4.4 Supramolecular Systems
4.4.1 Cyclophanes
4.4.2 Supramolecular Cages
4.5 Solid-State Reactions
4.5.1 Photocyclization
4.5.2 Gas–Solid Reactions
4.6 Biocatalysis
4.6.1 Enzymes
4.6.2 Catalytic Antibodies
References
5 Materials Science
5.1 Polymers
5.1.1 Supramolecular Polymers and Oligomers
5.1.2 Surface Modification of Polymers
5.1.3 Indole-Based Hydrogels
5.2 Biopolymer and Biomimetic Polymers
5.2.1 Mussel Underwater Adhesion
5.2.2 Mussel-Inspired Polymers
5.2.3 Lignin Biopolymers
5.3 Graphene-Based Materials
5.3.1 Graphene Oxide Membranes
5.3.2 Adsorption of Cationic Molecules
5.3.3 Dispersion of Graphenes
5.3.4 Formation of Non-Stoichiometric NaxCl Crystals
5.4 Energy-Related Materials
5.4.1 Energy Generation Systems
5.4.2 Energy Storage Systems
5.5 Fluorophores
5.5.1 Fluorescent-Switch Polymers
5.5.2 HaloTag Fluorogenic Probes
5.5.3 Sensors for Alkyl Halides
5.5.4 Aggregation-Induced Emission Luminogens
5.5.5 Intercalation-Induced Emission Systems
5.6 Recognition-Based Materials
5.6.1 Cavitand Receptors for AFM Prove Recognition
5.6.2 Sumanene–Ferrocene Conjugates for Cs+ Recognition
References