دانلود کتاب Introduction to Industrial Polyethylene : Properties, Catalysts, and Processes

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Content: Cover13; --
Introduction to Industrial Polyethylene --
Contents --
Preface --
List of Tables --
List of Figures --
Chapter 1 Introduction to Polymers of Ethylene --
1.1 Genesis of Polyethylene --
1.2 Basic Description of Polyethylene --
1.3 Types and Nomenclature of Polyethylenes --
1.4 Molecular Weight of Polyethylenes --
1.5 Transition Metal Catalysts for Ethylene Polymerization --
Chapter 2 Free Radical Polymerization of Ethylene --
2.1 Introduction --
2.2 Free Radical Polymerization of Ethylene --
2.3 Organic Peroxide Initiators --
Chapter 3 Ziegler-Natta Catalysts --
3.1 A Brief History of Ziegler-Natta Catalysts --
3.2 Definitions and Nomenclature --
3.3 Characteristics of Ziegler-Natta Catalysts --
3.4 Early Commercial Ziegler-Natta Catalysts --
3.5 Supported Ziegler-Natta Catalysts --
3.6 Prepolymerized Ziegler-Natta Catalysts --
3.7 Mechanism of Ziegler-Natta Polymerization --
Chapter 4 Metal Alkyls in Polyethylene Catalyst Systems --
4.1 Introduction --
4.2 Aluminum Alkyls in Ziegler-Natta Catalysts --
4.2.1 Reducing Agent for the Transition Metal --
4.2.2 Alkylating Agent for Creation of Active Centers --
4.2.3 Scavenger of Catalyst Poisons --
4.2.4 Chain Transfer Agent --
4.3 Magnesium Alkyls in Ziegler-Natta Catalysts --
4.3.1 R2Mg for Production of Supports --
4.3.2 R2Mg as Reducing Agent --
4.4 Lithium Alkyls --
4.5 Organoboron Compounds --
4.6 Zinc Alkyls --
4.7 Safety and Handling of Metal Alkyls --
Chapter 5 Chromium Catalysts --
5.1 Chromium Catalysts Supported on Metal Oxides --
5.2 Basic Chemistry of Phillips Catalysts --
5.3 Generations of Phillips Catalysts --
5.4 Union Carbide Chromium Catalysts --
5.5 Mechanism of Polymerization with Supported Chromium Catalysts --
Chapter 6 Single Site Catalysts --
6.1 Introduction --
6.2 Metallocene Single Site Catalysts --
6.2.1 Non-metallocene Single Site Catalysts --
6.3 Cocatalysts for Single Site Catalysts --
6.3.1 Methylaluminoxanes --
6.3.2 Arylboranes --
6.3.3 Other Cocatalysts for Single Site Catalysts --
6.4 Mechanism of Polymerization with Single Site Catalysts --
Chapter 7 An Overview of Industrial Polyethylene Processes --
7.1 Introduction --
7.2 High Pressure Processes --
7.2.1 Autoclave Process --
7.2.2 Tubular Process --
7.3 Slurry (Suspension) Process --
7.4 Gas Phase Process --
7.5 Solution Process --
7.6 Combined Processes --
Chapter 8 Downstream Aspects of Polyethylene --
8.1 Introduction --
8.2 Additives --
8.3 Melt Processing --
8.4 Markets --
8.5 Environmental --
Glossary --
Trade Name Index --
Index
Abstract: